We demonstrate a new all-optical, frequency-multiplexed, and fast technique for gas-phase ultrasonic absorption spectroscopy. A pulsed laser produces a short-duration acoustic pulse in the gas sample, and the acoustic pulse profiles at two distances are monitored by focused continuous probe beams. Fourier decompositions of these probe deflection signals provide the absorption spectrum, and examples for C0 2 and a C0 2 + H 2 0 mixture are given. Ultrasonic propagation speeds in the megahertz regime are also obtained for several gases. PACS numbers: 42.60.-v, 34.50.-s, 43.85.+fConventional acoustic absorption spectroscopy 1 " 5 in gases has been performed with transducers such as quartz plates, microphones, etc. The use of transducers for gases causes several limitations. The frequency response is usually limited to < 1 MHz. Also, the frequencies are scanned point by point, and the procedure is thus slow and unsuitable for transient conditions. Short-pulsed measurements are difficult because of transducer ringing. Furthermore, transducers cannot be used in hostile environments like flames. We describe here a new all-optical, pulsed, and multiplexed technique that avoids the above limitations, and is useful for acoustic absorption spectroscopy of gases. This technique relies on the use of a short-duration laser pulse to generate reliably a narrow acoustic pulse containing a broad Fourier frequency spectrum; as this pulse propagates, the various Fourier components are absorbed differently, resulting in pulse distortion that is probed by a focused cw laser beam. Fast Fourier transform of the transient probe deflection signal provides the acoustic absorption spectrum; this is much faster than the conventional pointwise frequency measurement. Our technique can be called "optoacoustic spectroscopy of the second kind" (OAS II) because it exploits optoacoustic pulse generation 6 " 8 for acoustic spectroscopy. This should be distinguished from the well-known optoacoustic spectroscopy 9 (understood to be the first kind), which exploits optoacoustic pulse generation for optical spectroscopy.Our experimental demonstration of OAS II is shown in Fig.