Nonbonding Electron Delocalization Stabilizes the Flexible N8 Molecular Assembly
Chuang Yao,
Kai-Le Dou,
Yezi Yang
et al.
Abstract:Electron delocalization has an important impact on the physical properties of condensed materials. However, the L-electron delocalization in inorganic, especially nitrogen, compounds needs exploitation to improve the energy efficiency, safety, and environmental sustainability of high-energy-density materials (HEDMs). This Letter presents an intriguing N 8 molecule, ingeniously utilizing nitrogen's L-electron delocalization. The molecule, exhibiting a unique lollipop-shaped conformation, can fold at various ang… Show more
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