2014
DOI: 10.1051/epjconf/20147505007
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Non-uniform coupling model of the frustrated chromium-based ring Cr8Ni

Abstract: Abstract. A numerically exact spin-Hamiltonian approach has been proposed for the frustrated Cr 8 Ni molecule. The non-uniform exchange couplings parameters, improving the fit of the experimental magnetic susceptibility data, have been obtained, using a genetic algorithm search procedure. The energy intervals between the lowest multiplets, relevant for envisaged transitions observable in the INS spectra, have been determined and the critical fields corresponding to the first-level crossing have been estimated … Show more

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Cited by 6 publications
(2 citation statements)
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“…Single-ion anisotropy plays the crucial role in investigations of single-molecule magnets and in many cases of anisotropic models some features analogous to LMLO are also observed [33,35,36,48,49]. However, in such cases the total spin is not a good quantum number, so the LMLO should be rather related to the total magnetization.…”
Section: Conclusion and Final Remarksmentioning
confidence: 99%
See 1 more Smart Citation
“…Single-ion anisotropy plays the crucial role in investigations of single-molecule magnets and in many cases of anisotropic models some features analogous to LMLO are also observed [33,35,36,48,49]. However, in such cases the total spin is not a good quantum number, so the LMLO should be rather related to the total magnetization.…”
Section: Conclusion and Final Remarksmentioning
confidence: 99%
“…Moreover, it can be proved (in some cases numerically only) that larger, non-bipartite in general, analogous of bipartite systems still exhibit the LMLO [30][31][32]. Similarly, this effect is observed for anisotropic systems, but the total spin number S has to be replaced by the total magnetization M [33][34][35][36]. Reformulation of the LMT to include all these cases is a challenging task and to complete it, this theorem itself has to be 'revisited' and mathematical background must be meticulously examined.…”
Section: Introductionmentioning
confidence: 96%