Non‐isothermal Decomposition Kinetics, Specific Heat Capacity and Adiabatic Time‐to‐explosion of a High Energy Material: 4,6‐Bis(5‐amino‐3‐nitro‐1,2,4‐triazol‐1‐yl)‐5‐nitropyrimidine

Abstract

The thermal behavior of 4,6-bis-(5-amino-3-nitro-1,2,4-triazol-1-yl)-5-nitropyrimidine (BANTNP) was studied under a non-isothermal condition by DSC, PDSC and TG/DTG methods. The critical temperature of thermal explosion is 588.28 K. The specific heat capacity of BANTNP was determined with a Micro-DSC method, and the standard molar specific heat capacity is 397.54 J•mol -1 •K -1 at 298.15 K. The adiabatic time-to-explosion of BANTNP was calculated to be 11.75 s.

Thermal Behavior of Sr(II) and Ba(II)‐Diclofenac Complexes in Solid State: Study of the Dehydration and Thermal Decomposition

“…metal complexes. Thus, thermal analysis reveals information on the thermal behavior, such as stoichiometry, 1 dehydration and decomposition stages, [2][3][4] energetic materials, 5,6 flame retardants, 7 and cure processes, 8 etc. However, in this work we use the dehydration and decomposition stages technique to study and obtain information about the thermal behavior of strontium and barium-diclofenac complexes.…”