Abstract:In this report, CeO2 and SiO2 supported 1 wt% Ru catalysts were synthesized and studied for dry reforming of methane (DRM) by introducing non-thermal plasma (NTP) in a dielectric barrier...
“…The application of CeO 2 can enhance the metal–ceria interaction and suppress carbon deposition through the redox cycles of Ce 3+ and Ce 4+ under a reductive atmosphere during the DRM reaction. 184,185 Previous experimental and theoretical studies showed that ceria-supported catalysts had strong metal–support interaction, which greatly improved the catalyst stability. In addition, the redox property of the catalyst is also affected by the morphology of Ce.…”
Section: Physical and Chemical Properties Of Co-based Catalysts For Drmmentioning
Dry reforming of methane (DRM) can effectively alleviate problems such as energy shortage and serious greenhouse effect. The properties of catalytic materials directly affect the performance of DRM. With the...
“…The application of CeO 2 can enhance the metal–ceria interaction and suppress carbon deposition through the redox cycles of Ce 3+ and Ce 4+ under a reductive atmosphere during the DRM reaction. 184,185 Previous experimental and theoretical studies showed that ceria-supported catalysts had strong metal–support interaction, which greatly improved the catalyst stability. In addition, the redox property of the catalyst is also affected by the morphology of Ce.…”
Section: Physical and Chemical Properties Of Co-based Catalysts For Drmmentioning
Dry reforming of methane (DRM) can effectively alleviate problems such as energy shortage and serious greenhouse effect. The properties of catalytic materials directly affect the performance of DRM. With the...
“…According to reports, integrating energy levels into heterogeneous structures of composite semiconductor photocatalysts can effectively suppress light-induced recombination of charge carriers. − The formation of heterogeneous structures can significantly improve the spatial charge separation effect, prolong the lifetime of charge carriers, and thus greatly enhance the photocatalytic performance . To achieve such a photoanode system, an n-type metal oxide semiconductor is commonly employed due to its ability to perform the anodic OER reaction without semiconductor degradation in highly oxidizing electrochemical environments. , Cerium oxide (CeO 2 ) has been proven to exhibit excellent photocatalytic performance in the degradation of various organic dye pollutants, owing to its high oxygen storage capacity, catalytic reactions involving Ce 3+ /Ce 4+ ion pairs, environmental friendliness, and cost-effectiveness .…”
In order to solve the problem of slow water oxidation kinetics and charge complexation of the BiVO 4 photoanode, CeO 2 octahedral nanomaterials doped with different amounts of NaH 2 PO 4 (COP3) were synthesized by a hydrothermal method in one step. CeO 2based materials have been widely studied in the fields of organic catalysis, photocatalysis to decompose water, and photodegradation of organic pollutants, showing excellent photocatalytic properties. The heterostructure formed by MW:BVO and COP3 (doped with 0.002 g of NaH 2 PO 4 ) expands the light absorption range and accelerates the separation of the internal carriers. In order to further improve the photocatalytic performance, the MW:BVO/COP3@NiFeOOH (immersion time of 1 h and pH = 8, respectively) composite was prepared by introducing NiFeOOH. As a metal oxide coating additive, NiFeOOH can rapidly capture holes and effectively use these holes for water oxidation on the photoelectrode surface through a cyclic catalytic process. In addition, MW:BVO/COP3@NiFeOOH nanocomposites can effectively increase the active surface area and accelerate the interfacial charge transfer. The final prepared MW:BVO/COP3@NiFeOOH nanocomposites showed excellent photocurrent density (4.8 mA cm −2 at 1.23 V vs RHE) in LSV tests due to the efficient separation and transfer of photogenerated carriers. It can be seen that the interaction between MW:BVO, COP3, and NiFeOOH not only improves the performance of this new class of materials but also highlights the importance of COP3 as an important component worthy of further study.
“…As a result, they can immobilize and convert polysulfides, thus reducing their migration and alleviating capacity degradation. 45,46,49 When cerium is introduced into Li 2 S-P 2 S 5 (LPS), the defect structure and/or conentration of the material can be modified, thereby enhancing the migration of Li + ions, resulting in an improvement in the ionic conductivity of the material. It is believed that a significant part of this enhancement can be attributed to the introduction of additional mobile charge carriers and the optimization of the Li-ion diffusion pathways.…”
Section: Introductionmentioning
confidence: 99%
“…The cerium ions (Ce 4+ /Ce 3+ ) can act both as redox mediators and as redox catalysts in Li‐S battery due to their variable oxidation states. As a result, they can immobilize and convert polysulfides, thus reducing their migration and alleviating capacity degradation 45,46,49 . When cerium is introduced into Li 2 S‐P 2 S 5 (LPS), the defect structure and/or conentration of the material can be modified, thereby enhancing the migration of Li + ions, resulting in an improvement in the ionic conductivity of the material.…”
Section: Introductionmentioning
confidence: 99%
“…6 Carbon dioxide and other pollutants (including greenhouse gases) are reduced in the atmosphere when energy storage devices store energy from renewable sources. 7,8 In this way, global warming and other environmental problems can be mitigated. Currently, lithium-ion battery is undeniably one of the greatest triumphs of modern electrochemistry storage devices due to its high single-cell voltage, lack of memory effect, long cycle life, and high energy density.…”
In this report, a facile wet chemical method using acetonitrile combined with thermal annealing was used to prepare Li2S‐P2S5 (LPS) based glass‐ceramic electrolytes with (1 wt%, 3 wt%, and 5 wt% Ce2S3) and without Ce2S3 doping. The crystal structure, ionic conductivity, and chemical stability of Li7P3S11 glass‐ceramic electrolytes were examined at varying temperatures (250–350°C). The results indicated that the highest ionic conductivity of 3.15 × 10−4 S cm−1 for pure Li7P3S11 was observed at a temperature of 325°C. By incorporating 1 wt% Ce2S3 and subjecting it to a heat treatment at 250°C, the glass ceramic electrolyte attained a remarkable ionic conductivity of 7.7 × 10−4 (S cm−1) at 25°C. Furthermore, it exhibited a stable and extensive electrochemical potential range, reaching up to 5 volts when compared to the Li/Li+ reference electrode. By tuning the glass transition and crystallization temperature, cerium doping seems to make Li7P3S11 more chemically stable, compared to its original 70Li2S‐30P2S5 counterpart. According to Raman and X‐ray photoelectron spectroscopy analyses, cerium doping inhibits the decomposition of highly conductive P2S74‐ (pyro‐thiophosphate) to PS43− and P2S64−. Doped LPS has a greater crystallinity and more uniform microstructure than pure LPS, according to XRD, Raman spectroscopy, and scanning electron microscopy analysis. Consequently, Li7P2.9Ce0.1S11 electrolyte shows great potential as a solid‐state electrolyte for constructing high‐performance sulfide‐based all‐solid‐state batteries.
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