“…A major advantage of pXRF is that instruments can be transported to study objects in situ, thereby permitting multi-element analyses of archaeological materials in non-traditional laboratory environments. However, archaeological applications of pXRF are still today an object of discussion (Liritzis, & Zacharias, 2010;Tykot, et al, 2013), principally because of a perceived lack of analytic rigour (Shackley, 2010(Shackley, , 2012Grave, Attenbrow, Sutherland, Pogson & Forster, 2012;Speakman & Shackley, 2013;Frahm & Doonan, 2013). The present work contributes to this debate regarding pXRF through the study of Caltagirone pottery raw materials.…”