Non-covalent dynamic exchange mechanism of intrinsic self-healing at 20 °C in polyurethane due to interactions among carbonate groups of the soft segments
Yuliet Paez-Amieva,
José Miguel Martín-Martínez
Abstract:Two polyurethanes (PUs) were similarly synthesized by reacting a cycloaliphatic isocyanate with 1,4 butanediol and two polyols of different nature (polyester, polycarbonate diol) with molecular weights of 1000 Da. The PU made with polycarbonate diol polyol (YCD) was the only showing intrinsic self-healing at 20 °C. For assessing the mechanism of intrinsic self-healing of YCD, a structural characterization by molecular weights determination, infrared and X-ray photoelectronic spectroscopies, differentia… Show more
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