“…Electrochemical water splitting is a promising approach to obtain green hydrogen, which is not only a sustainable energy source for vehicles but also a crucial feedstock in chemical industry. − In the electrochemical water splitting process, oxygen evolution reaction (OER) occurrs at the anode, and hydrogen evolution reaction (HER) occurrs at the cathode, , for which metal oxides and noble metal are the benchmark catalysts, respectively. , Till now, multiple transition metal-based materials such as oxides, − hydroxides, , sulfides, − phosphides, − phosphates, , carbides, − and nitrides, , have been developed as catalysts for OER, HER, and overall water splitting. Among the above-mentioned catalysts, transition metal metaphosphates (TMMPs) with abundant MO x and PO 4 units have received growing interest since the Fe(PO 3 ) 3 -Ni 2 P catalysts were reported with extremely high OER activity (177 mV at 10 mA cm –2 ) and stability .…”