NO Oxidation by Activated Carbon Catalysts: Impact of Carbon Characteristics, Pressure, and the Presence of Water

Abstract

Nitric oxide can be removed from flue gas by catalytic oxidation of NO to NO 2 , followed by dissolution of NO 2 in water. The work presented here includes catalytic NO oxidation by activated carbons (ACs) at atmospheric and elevated pressures under dry and wet conditions at ambient temperature. The AC samples had different physicochemical characteristics including surface areas of ∼400–1600 m 2 /g and micropore volumes of ∼0.2–0.6 cm 3 /g while having different surface chemistries. Dry tests indicated that introducing nitrogen functionalities or coating with pyrolytic carbon could enhance the catalytic activity of AC for NO oxidation. Nitric oxide concentration profiles from the oxidation experiments under dry conditions showed maximum values after 5–15.5 h of testing and a steady-state condition after ∼12–30 h and that a major release of NO 2 began after reaching the maximum values in the NO concentration. Adsorption profiles showed a high rate of NO x adsorption during the early hours of these experiments, and this rate decreased almost exponentially to a near-zero value. A near-complete catalytic conversion was achieved for NO oxidation at 120 psig under dry conditions, substantially higher than the 62% value of the noncatalytic NO oxidation at 217 psig. The wet trickle-bed experiments revealed that an inert packing material with a high external surface was a more suitable option than the ACs for NO oxidation in a wet trickle-bed system, even for ACs that exhibited high catalytic reactivity under dry conditions. Noncatalytic NO oxidation in the trickle-bed system was enhanced by the higher gas–liquid contact surface of the packing material for NO 2 dissolution in water. Complete wetting of the hydrophilic AC or the presence of water vapor in the gas in contact with the surface of the superhydrophobic AC could eliminate or drastically reduce the catalytic activity of the AC for NO oxidation.

Simultaneous removal of SO2 and NOx from flue gas by low-temperature adsorption over activated carbon

“…The inlet gas has flow rate of 1 L/min, and is composed of NO (200 ppmv), O 2 (6 vol.%) and N 2 . With the presence of oxygen, NO can be oxidized to NO 2 over activated carbon 22 , 23 , a steady NO–NO 2 equilibrium will be formed at the exit of activated carbon bed 24 , 25 . Therefore, the concentration of both NO and NO 2 at the outlet of adsorption bed is measured and plotted in Fig.…”

Simultaneous Removal of SO2 and NOx From Flue Gas by Low-temperature Adsorption Over Activated Carbon

“…With the presence of oxygen, NO can be oxidized to NO2 over activated carbon [20,21], a steady NO-NO2 equilibrium will be formed at the exit of activated carbon bed [22,23]. For NO-O2 co-adsorption over CAC at various temperature, the time-dependent concentration of NO and NO2 at the exit of adsorption pipe is given in Fig.7.…”

Revealing the Tunable Effects of Single Metal Atoms Supported on Nitrogen-Doped Carbon Nanotubes during NO Oxidation from Microkinetic Simulation

“…In the presence of oxygen, NO can be oxidized to NO 2 over activated carbon, 24 and the conversion is over 90% at room temperature of activated carbon. 25,26 Recently, single atom catalysts (SACs) have attracted extensive attention with good selectivity and durability. 27,28 In particularly, in principle, SACs could reach a 100% atom efficiency and significantly reduce the noble metal usage.…”