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The article contains sections titled: 1. Introduction 2. Biological Nitrogen Fixation 2.1. Microorganisms 2.2. Nitrogenases 2.3. Reaction Stoichiometry and Mechanism 2.4. Genetic Control of Nitrogenases 3. Reactions of Dinitrogen 3.1. Reaction with Metals and Metal Complexes 3.2. Activation of Dinitrogen for Ammonia Formation 3.3. Structures of Dinitrogen Complexes 4. Protonation and Alkylation of Dinitrogen Complexes 4.1. End‐on Dinitrogen Complexes 4.2. Bridging Dinitrogen Complexes 5. Mechanisms of Reactions of Coordinated Dinitrogen 6. Fixing Systems Involving Chemical Reduction of Dinitrogen Before N−H Bond Formation 6.1. Nitriding Systems 6.2. Cyclopentadienyltitanium Systems 7. Nitrogen Fixation in Protic Solvents 8. Other Aqueous Fixation Systems 8.1. Approaches to Models for Nitrogenases 8.2. Mechanisms 9. Fixation of Nitrogen Involving Metal Clusters 10. Photochemical Fixation Processes 11. Oxidative Fixation Processes
The article contains sections titled: 1. Introduction 2. Biological Nitrogen Fixation 2.1. Microorganisms 2.2. Nitrogenases 2.3. Reaction Stoichiometry and Mechanism 2.4. Genetic Control of Nitrogenases 3. Reactions of Dinitrogen 3.1. Reaction with Metals and Metal Complexes 3.2. Activation of Dinitrogen for Ammonia Formation 3.3. Structures of Dinitrogen Complexes 4. Protonation and Alkylation of Dinitrogen Complexes 4.1. End‐on Dinitrogen Complexes 4.2. Bridging Dinitrogen Complexes 5. Mechanisms of Reactions of Coordinated Dinitrogen 6. Fixing Systems Involving Chemical Reduction of Dinitrogen Before N−H Bond Formation 6.1. Nitriding Systems 6.2. Cyclopentadienyltitanium Systems 7. Nitrogen Fixation in Protic Solvents 8. Other Aqueous Fixation Systems 8.1. Approaches to Models for Nitrogenases 8.2. Mechanisms 9. Fixation of Nitrogen Involving Metal Clusters 10. Photochemical Fixation Processes 11. Oxidative Fixation Processes
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