“…[ 23,37,74,187 ] Theoretically, the main driving force for CDs’ electron transferring is the energy gap between the LUMO of donors and acceptors, and the CDs’ fluorescence quenching is more likely to occur with the stronger electron absorption ability of acceptors. [ 147,156 ] In Fe 3+ ‐induced fluorescence quenching (Figure 9c), the part of electrons or charges in excited LC‐CDs is induced to pass on the unsaturated Fe 3+ 3d electron orbitals, leading to an ineffective nonradiative transition that causes the fluorescence quenching. After that, the chelation between LC‐CDs and Fe 3+ can be reduced through introducing a reducing agent because of the reduced Fe 3+ valence, and the fluorescence intensity of LC‐CDs will gradually recover.…”
Section: Structures and Propertiesmentioning
confidence: 99%
“…g-j) AFM images of LC-CDs. (g) is reproduced with the permission [156]. Copyright 2021, Springer-Verlag GmbH Germany.…”
Carbon dots (CDs), a new type of carbon‐based fluorescent nanomaterial, have attracted widespread attention because of their numerous excellent properties. Lignocellulosic biomass is the most abundant renewable natural resource and possesses broad potential to manufacture different composite and smart materials. Numerous studies have explored the potential of using the components (such as cellulose, hemicellulose, and lignin) in lignocellulosic biomass to produce CDs. There are few papers systemically aiming in the review of the state‐of‐the‐art works related to lignocellulosic biomass‐derived CDs. In this review, the significant advances in synthesis processes, formation mechanisms, structural characteristics, optical properties, and applications of lignocellulosic biomass‐based CDs such as cellulose‐based CDs, hemicellulose‐based CDs and lignin‐based CDs in latest research are reviewed. In addition, future research directions on the improvement of the synthesis technology of CDs using lignocellulosic biomass as raw materials to enhance the properties of CDs are proposed. This review will serve as a road map for scientists engaged in research and exploring more applications of CDs in different science fields to achieve the highest material performance goals of CDs.
“…[ 23,37,74,187 ] Theoretically, the main driving force for CDs’ electron transferring is the energy gap between the LUMO of donors and acceptors, and the CDs’ fluorescence quenching is more likely to occur with the stronger electron absorption ability of acceptors. [ 147,156 ] In Fe 3+ ‐induced fluorescence quenching (Figure 9c), the part of electrons or charges in excited LC‐CDs is induced to pass on the unsaturated Fe 3+ 3d electron orbitals, leading to an ineffective nonradiative transition that causes the fluorescence quenching. After that, the chelation between LC‐CDs and Fe 3+ can be reduced through introducing a reducing agent because of the reduced Fe 3+ valence, and the fluorescence intensity of LC‐CDs will gradually recover.…”
Section: Structures and Propertiesmentioning
confidence: 99%
“…g-j) AFM images of LC-CDs. (g) is reproduced with the permission [156]. Copyright 2021, Springer-Verlag GmbH Germany.…”
Carbon dots (CDs), a new type of carbon‐based fluorescent nanomaterial, have attracted widespread attention because of their numerous excellent properties. Lignocellulosic biomass is the most abundant renewable natural resource and possesses broad potential to manufacture different composite and smart materials. Numerous studies have explored the potential of using the components (such as cellulose, hemicellulose, and lignin) in lignocellulosic biomass to produce CDs. There are few papers systemically aiming in the review of the state‐of‐the‐art works related to lignocellulosic biomass‐derived CDs. In this review, the significant advances in synthesis processes, formation mechanisms, structural characteristics, optical properties, and applications of lignocellulosic biomass‐based CDs such as cellulose‐based CDs, hemicellulose‐based CDs and lignin‐based CDs in latest research are reviewed. In addition, future research directions on the improvement of the synthesis technology of CDs using lignocellulosic biomass as raw materials to enhance the properties of CDs are proposed. This review will serve as a road map for scientists engaged in research and exploring more applications of CDs in different science fields to achieve the highest material performance goals of CDs.
“…Meanwhile, it provides a route for high-value utilization of lignin. Recently, the research studies of LCDs have been rapidly developed, and amounts of related synthesis methods have been reported. − …”
Lignin-based carbon dots (LCDs) have attracted increasing attention, but their limited regulation and the use of harmful chemicals in their preparation have hindered their applications. In this study, we successfully produced LCDs by heating lignin dissolved in a green solvent system, a binary solvent of γ-valerolactone (GVL) and water. Furthermore, we were able to easily regulate the fluorescence properties of the LCDs by adding environmentally friendly chemicals, such as urea and citric acid, to the lignin solution. As a result, the emitting fluorescence of the LCDs was shifted from blue light to yellow, and their fluorescence performances were significantly improved with a maximum relative quantum yield of 33.2%. In addition, we generated LCD-loaded lignin nanoparticles (LNPs) with a size of ∼200 nm in situ via solvent shifting. This simple method of producing LCDs or LCD-loaded LNPs can endow them with versatile functions and wide applications.
“…Great efforts have been made to develop different methods to determine Cyt c in human serum [8][9][10][11] with considerable attention on fluorescence techniques with new emerging luminescence nanomaterials. [12][13][14][15] For example, Yin et al developed a turn-off fluorescence method for Cyt c via electrostatic induction aggregation and static quenching on nitrogen-doped carbon quantum dots (N-CQDs). [12] Salehnia et al reported an aptamer-based fluorometric assay for cytochrome c by restoring the fluorescence of graphitic carbon nitride nanosheets.…”
Section: Introductionmentioning
confidence: 99%
“…[12][13][14][15] For example, Yin et al developed a turn-off fluorescence method for Cyt c via electrostatic induction aggregation and static quenching on nitrogen-doped carbon quantum dots (N-CQDs). [12] Salehnia et al reported an aptamer-based fluorometric assay for cytochrome c by restoring the fluorescence of graphitic carbon nitride nanosheets. [13] Metal nanoclusters (NCs) are a new class of luminescent nanomaterials composed of several to tens of metal atoms.…”
Quantitative determination of serum cytochrome c (Cyt c) is of importance in the regular medical assessment of cancer diseases. This work reported a new fluorescence method for the determination of Cyt c with glutathione‐protected gold nanoclusters (GSH‐AuNCs) as a signal reporter. Cyt c was observed to quench the fluorescence of GSH‐AuNCs due to its electron‐rich structure. This inhibitory effect was further strengthened by its peroxidase mimetic catalytic activity on hydrogen peroxide (H2O2)‐mediated oxidation of GSH‐AuNCs. The inhibitory efficiency was linearly related to Cyt c concentrations ranging from 10.0 to 700.0 nM with a limit of detection of 2.7 nM (3sb/S). The relative standard deviation was 3.6% for Cyt c at a 40.0 nM concentration level (n = 11). The practical application of the method was evaluated by the determination of Cyt c in spiked human serum samples. The recoveries were within the range from 92.6 to 104.8%, suggesting its potential application in biomedical and clinical diagnosis.
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