Nitrile Derivatives of Chromium Group Metal Carbonyls.

Tate, D. P.; Knipple, Warren R.; Augl, Joseph M.

doi:10.1021/ic50002a052

Cited by 425 publications

(124 citation statements)

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“…The main features recorded in these three spectra ( (6)(7)(8)(9)(10)(11) 0.92 (9) structure for the complexes in C6D6 solution similar to that demonstrated for [MeGa(N,C,H,),(OH)]-Mo(CO),(q3-C,H,) in the solid state (see Fig. 1).…”

Section: Hydroxy Complexessupporting

confidence: 73%

Complexes of the methyl tris(3,5-dimethylpyrazol-1-yl) gallate ligand, MeGa(N₂C₅H₇)₃⁻, and its hydroxy derivative, MeGa(N₂C₅H₇)₂(OH)⁻. Crystal and molecular structure of [MeGa(N₂C₅H₇)₂(OH)]Mo(CO)₂(η³-C₄H₇)

Breakell¹,

Rettig²,

Storr³

et al. 1979

Can. J. Chem.

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Section: Hydroxy Complexessupporting

confidence: 73%

Complexes of the methyl tris(3,5-dimethylpyrazol-1-yl) gallate ligand, MeGa(N₂C₅H₇)₃⁻, and its hydroxy derivative, MeGa(N₂C₅H₇)₂(OH)⁻. Crystal and molecular structure of [MeGa(N₂C₅H₇)₂(OH)]Mo(CO)₂(η³-C₄H₇)

Breakell¹,

Rettig²,

Storr³

et al. 1979

Can. J. Chem.

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“…(CH3CN)3Cr(CO)3 also been prepared but it shows extremely sensitivity and less stability. These compounds serves as excellent intermediates in the formation of new compounds not available by other routes [88].…”

Section: M(co)3(acetonitril)mentioning

confidence: 99%

The chemistry of group-VIb metal carbonyls

Kaushik¹,

Singh²,

Kumar³

2012

Eur. J. Chem.

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KEYWORDSThe special interest attached to the chemistry of metal carbonyls arises from several causes. While quite distinct from the metal carbonyls in the organometallic compounds, they differ in physical properties (e.g., their volatility) from all other compounds of the transition metals. Chemically, they constitute a group of compounds in which the formal valency of the metal atoms is zero, and in this respect (apart, perhaps, from the ammoniates of the alkali metals) they are comparable only with the recently discovered compounds. As a class, the carbonyls are reactive compounds, and a number of new types of inorganic compounds have been discovered. In the concepts for new products, performance, product safety, and product economy criteria are equally important. They are taken into account already when the raw material base for a new industrial product development is defined. Since the discovery of nickel carbonyl by Mond and Langer in 1888, the carbonyls of the iron group and of chromium, molybdenum and tungsten have found important technical applications, e.g., in the Mond nickel process, and for the preparation of the metals in a state of subdivision and of purity suitable for powder metallurgy, for catalysts, etc. The reaction mechanism of the processes developed for producing the carbonyls technically has only recently received its interpretations. Within the space of review it is necessary to limit discussion to a few topics. Particular stress has accordingly laid upon (a) the chemical bonding in metal carbonyls, (b) importance of IR and NMR spectroscopy in characterization of metal carbonyls, (c) substitution reactions of G-VIb metal carbonyls, (d) kinetics and mechanism of substitution reactions in metal carbonyls, (e) substituted complexes of G-VIb metal carbonyl, (f) chelate complexes of G-VIb metal carbonyls, (g) uses of G-VIb metal carbonyl complexes and (h) studies done on G-VIb metal carbonyls.

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“…Hexacarbonylchromium(O) was purchased from Ventron and used as received. Tricarbonyltris(acetonitrile)chromium(O) was prepared according to the known procedure [10 ].…”

Section: Methodsmentioning

confidence: 99%

Notizen: Synthesis and NM R Study of (η⁶-1,4-diphenyl-1,3-butadiene)tricarbonylchromium(0)

Kayran

Özkâr

1992

Zeitschrift Für Naturforschung B

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Nitrile Derivatives of Chromium Group Metal Carbonyls.

Cited by 425 publications

References 0 publications

Complexes of the methyl tris(3,5-dimethylpyrazol-1-yl) gallate ligand, MeGa(N₂C₅H₇)₃⁻, and its hydroxy derivative, MeGa(N₂C₅H₇)₂(OH)⁻. Crystal and molecular structure of [MeGa(N₂C₅H₇)₂(OH)]Mo(CO)₂(η³-C₄H₇)

Complexes of the methyl tris(3,5-dimethylpyrazol-1-yl) gallate ligand, MeGa(N₂C₅H₇)₃⁻, and its hydroxy derivative, MeGa(N₂C₅H₇)₂(OH)⁻. Crystal and molecular structure of [MeGa(N₂C₅H₇)₂(OH)]Mo(CO)₂(η³-C₄H₇)

The chemistry of group-VIb metal carbonyls

Notizen: Synthesis and NM R Study of (η⁶-1,4-diphenyl-1,3-butadiene)tricarbonylchromium(0)

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Nitrile Derivatives of Chromium Group Metal Carbonyls.

Cited by 425 publications

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Complexes of the methyl tris(3,5-dimethylpyrazol-1-yl) gallate ligand, MeGa(N2C5H7)3−, and its hydroxy derivative, MeGa(N2C5H7)2(OH)−. Crystal and molecular structure of [MeGa(N2C5H7)2(OH)]Mo(CO)2(η3-C4H7)

Complexes of the methyl tris(3,5-dimethylpyrazol-1-yl) gallate ligand, MeGa(N2C5H7)3−, and its hydroxy derivative, MeGa(N2C5H7)2(OH)−. Crystal and molecular structure of [MeGa(N2C5H7)2(OH)]Mo(CO)2(η3-C4H7)

The chemistry of group-VIb metal carbonyls

Notizen: Synthesis and NM R Study of (η6-1,4-diphenyl-1,3-butadiene)tricarbonylchromium(0)

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Complexes of the methyl tris(3,5-dimethylpyrazol-1-yl) gallate ligand, MeGa(N₂C₅H₇)₃⁻, and its hydroxy derivative, MeGa(N₂C₅H₇)₂(OH)⁻. Crystal and molecular structure of [MeGa(N₂C₅H₇)₂(OH)]Mo(CO)₂(η³-C₄H₇)

Complexes of the methyl tris(3,5-dimethylpyrazol-1-yl) gallate ligand, MeGa(N₂C₅H₇)₃⁻, and its hydroxy derivative, MeGa(N₂C₅H₇)₂(OH)⁻. Crystal and molecular structure of [MeGa(N₂C₅H₇)₂(OH)]Mo(CO)₂(η³-C₄H₇)

Notizen: Synthesis and NM R Study of (η⁶-1,4-diphenyl-1,3-butadiene)tricarbonylchromium(0)