2008
DOI: 10.1016/j.jnoncrysol.2008.06.072
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Nitridation of SiO2–B2O3 aerogels

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Cited by 8 publications
(2 citation statements)
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“…Table 2 lists a series of different species that can be used to fabricate oxide gels and/or for usage in sol‐gel techniques that sometimes yield non‐gel products. [ 2,25–41 ] Some of these reactants are liquids at room temperature, some are solids, and some are dissolved (or suspended) in a secondary liquid, which is typically an alcohol (e.g., methanol, ethanol, isopropanol). The hydrolysis rates of metal alkoxides vary widely where some compounds are quite stable in air (e.g., TEOS) while others can hydrolyze readily in air [e.g., aluminum tri‐ sec ‐butoxide or Al(OBu s ) 3 , sodium ethoxide or NaOEt] and require storage and handling in an inert atmosphere such as a nitrogen glovebox.…”
Section: Synthesis Methodsmentioning
confidence: 99%
“…Table 2 lists a series of different species that can be used to fabricate oxide gels and/or for usage in sol‐gel techniques that sometimes yield non‐gel products. [ 2,25–41 ] Some of these reactants are liquids at room temperature, some are solids, and some are dissolved (or suspended) in a secondary liquid, which is typically an alcohol (e.g., methanol, ethanol, isopropanol). The hydrolysis rates of metal alkoxides vary widely where some compounds are quite stable in air (e.g., TEOS) while others can hydrolyze readily in air [e.g., aluminum tri‐ sec ‐butoxide or Al(OBu s ) 3 , sodium ethoxide or NaOEt] and require storage and handling in an inert atmosphere such as a nitrogen glovebox.…”
Section: Synthesis Methodsmentioning
confidence: 99%
“…In this range an overlap of asymmetric stretching of Si-O and B-O vibrations takes place. It has been turned out that the absorption band at 1000-1500 cm -1 is characteristic for triangular BO 3 units [17]. This indicates that boron ions in Na 2 O-B 2 O 3 -SiO 2 aerogel are three coordinated.…”
Section: Resultsmentioning
confidence: 99%