Abstract:The disproportionation of nitric oxide was studied by FTIR with two different Rh(I)PCN complexes as mediators (PCN 1‐((diethylamino)methyl) ‐3‐((di‐tertbutylphosphino)methyl)‐benzene). As had already been reported for a PCP analogue, reaction yielded a Rh(PCN)(NO)(NO2) complex along with gaseous N2O in both cases. However, when [Rh(PCN)(NO)]⋅ was used as a reactant, FTIR monitoring allowed for the detection of signals of a reaction intermediate, coherent with the expected but seldom reported dinitrosyl species … Show more
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