NiTi-layered double hydroxide as an efficient photocatalytic fungicide of Aspergillus fumigatus spores: Capacity and mechanism

Efficient one-pot syntheses of secondary amines from nitro aromatics and benzyl alcohols over Pd/NiTi-LDH under visible light

“…2b). 37,38 The presence of oxygen vacancies in the as-obtained 2.0 wt% Pd/NiTi-LDH could be further confirmed from its ESR result from a peak with its g value centered at 2.003 (ESI Fig. S1†).…”

“…2b). 37,38 The presence of oxygen vacancies in the asobtained 2.0 wt% Pd/NiTi-LDH could be further confirmed from its ESR result from a peak with its g value centered at The XPS results clearly indicate that the presence of highvalent-state Pd δ+ in metallic Pd nanoparticles is due to a partial electron transfer from metallic Pd to cationic Ti via the bridging oxygen in the as-obtained 2.0 wt% Pd/NiTi-LDH. The formation of a similar Pd-O-Ti bond was also reported previously in a Pd/ZnTi-LDH nanocomposite.…”