[NiII(tn)2]5[FeIII(CN)6]2[FeII(CN)6]·10H2O: A 3-dimensional dimetallic polymer exhibiting ferromagnetic interaction

2008) Synthesis, crystal structures and magnetic properties of a series of new cyanobridged complexes derived from templates [Ni(CN) 4 ] 2-and [Co(III)(CN) 6 ] 3-, Journal of Coordination Chemistry, 61:4, 550-562, Three new cyano-bridged complexes 1 [Ni(tn) 2 Ni(CN) 4been assembled by the templates [Ni(CN) 4 ] 2À and [Co(CN) 6 ] 3À . 1 consists of a one-dimensional linear chain -Ni(tn) 2 -NC-Ni(CN) 2 -CN-Ni(tn) 2À in which the Ni(II) centers are linked by two CN groups. One 1-D zigzag chain of 2 is formed with -Ni(2)-C-N-Cu(1)-N-C-linkages. A 2D structure of 3 is formed by an alternate array of [Co(CN) 6 ] 3À and [Co][Cu 6 ] units. For 1, there is an overall weak antiferromagnetic interaction between Ni(II) ions through the -NC-Ni-CN-bridges of the diamagnetic [Ni(CN) 4 ] 2À anions. 2 exhibits a weak antiferromagnetic exchange interaction between copper(II) ions mediated by [Ni(CN) 4 ] 2À diamagnetic bridges. Complex 3 exhibits a weak ferromagnetic interaction between nearest Cu II and Cu II atoms through -NC-Co-CN-bridges.

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[NiII(tn)2]5[FeIII(CN)6]2[FeII(CN)6]·10H2O: A 3-dimensional dimetallic polymer exhibiting ferromagnetic interaction

Cited by 7 publications

References 21 publications

A coexistence of ferromagnetic and antiferromagnetic exchange interactions in prussian blue analog Cu0.47Ni0.48Mn0.55[Fe(CN)6]·XH2O

A coexistence of ferromagnetic and antiferromagnetic exchange interactions in prussian blue analog Cu0.47Ni0.48Mn0.55[Fe(CN)6]·XH2O

Dinuclear and polynuclear silver(I) saccharinate complexes with 1,3-diaminopropane and N-methylethylenediamine constructed from Ag⋯C interactions

Synthesis, crystal structures and magnetic properties of a series of new cyano-bridged complexes derived from templates [Ni(CN)₄]²⁻ and [Co(III)(CN)₆]³⁻

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[NiII(tn)2]5[FeIII(CN)6]2[FeII(CN)6]·10H2O: A 3-dimensional dimetallic polymer exhibiting ferromagnetic interaction

Cited by 7 publications

References 21 publications

A coexistence of ferromagnetic and antiferromagnetic exchange interactions in prussian blue analog Cu0.47Ni0.48Mn0.55[Fe(CN)6]·XH2O

A coexistence of ferromagnetic and antiferromagnetic exchange interactions in prussian blue analog Cu0.47Ni0.48Mn0.55[Fe(CN)6]·XH2O

Dinuclear and polynuclear silver(I) saccharinate complexes with 1,3-diaminopropane and N-methylethylenediamine constructed from Ag⋯C interactions

Synthesis, crystal structures and magnetic properties of a series of new cyano-bridged complexes derived from templates [Ni(CN)4]2− and [Co(III)(CN)6]3−

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Synthesis, crystal structures and magnetic properties of a series of new cyano-bridged complexes derived from templates [Ni(CN)₄]²⁻ and [Co(III)(CN)₆]³⁻