Nickel-Сatalyzed Carbon–Selenium Bond Formations under Mild Conditions

Zhumagazy, Serik; Zhu, Chen; Yue, Huifeng; Rueping, Magnus

doi:10.1055/s-0042-1752655

Cited by 3 publications

(1 citation statement)

References 48 publications

(12 reference statements)

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“…28 Rueping and Yue describe a Ni-catalyzed technique for incorporating selenium atoms at sp 2 sites with aryl iodides as counterparts. 29 Following up on their interest in C-H functionalization, Chen and Zhao report a radical-based approach for accessing isoindolinones with ammonium persulfate as the oxidant. 30 Zhou and Yu describe the utilization of Cp*Rh(III)Cl 2 catalysts for enabling a series of transfer hydrogenation events with isopropanol as the hydride source.…”

Section: Cluster Synlettmentioning

confidence: 99%

Cluster Preface: Special Issue Honoring Masahiro Murakami’s Contributions to Science

Martı́n¹

2023

Synlett

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Ruben Martin (left) was born in Barcelona in 1976. After receiving his PhD at the Universitat de Barcelona with Prof. Antoni Riera, he moved in January 2004 to the Max-Planck-Institut für Kohlenforschung, Mülheim, as a Humboldt postdoctoral fellow with Prof. Alois Fürstner, where he worked on iron cross-coupling reactions. In May 2005, he undertook further postdoctoral studies at the Massachusetts Institute of Technology with Prof. Stephen L. Buchwald where he developed new metal-catalyzed C–C and C–N bond-forming reactions. In September 2008, he initiated his independent career as an Assistant Professor at ICIQ (Tarragona). In July 2013, he was promoted to Associate Professor and subsequently to ICREA Research Professor. His research interests concern the discovery and development of synthetically useful organometallic methodologies. Masahiro Murakami (right) studied chemistry at the University of Tokyo under the supervision of Professor Mukaiyama, receiving his doctoral degree in science in 1984. He started his career with a research assistant position to Professor Mukaiyama at the same place. In 1987, he moved to Kyoto University to take a research assistant position to the late Professor Yoshihiko Ito (1937–2006). He took a leave from May in 1991 to March in 1992 to work for Professor Albert Eschenmoser at ETH Zürich as a post-doctoral fellow. He then returned to Kyoto, being promoted to Associate Professor in 1993 and Professor in 2002. In March 2022, he retired from Kyoto University. His research interests include the development of synthetically useful, yet mechanistically interesting, organic sections, and the utilization of photo-energy for organic synthesis.

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Section: Cluster Synlettmentioning

confidence: 99%

Cluster Preface: Special Issue Honoring Masahiro Murakami’s Contributions to Science

Martı́n¹

2023

Synlett

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Bio-inspired Halogen Bonding-Promoted Cross Coupling for the Synthesis of Organoselenium Compounds

Li,

Yi,

Maity

et al. 2023

ACS Catal.

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Noncovalent interactions play fundamental roles in many organic and biochemical processes, including hydrogen and halogen bonding, which are vital in the fields of synthesis and catalysis. Herein, we describe the application of halogen bonding interactions to facilitate the reaction balance between an electron donor–acceptor (EDA) complex and Ph2Se2 for the synthesis of a series of organoselenium compounds. The EDA complex concept has recently emerged as an attractive path for visible light-induced transformations due to facile reaction conditions and the avoidance of photocatalysts. Density functional theory calculations reveal that an iodine–π* interaction leads to the formation of an alkyl radical from the N-(acyloxy)phthalimide ester. The resulting alkyl radical is captured by the diselenide–I• complex to form the C–Se bond. The developed selenide synthesis strategy has been applied in the transformation of primary, secondary, and tertiary carboxylic acids as well as a series of natural products, drugs, and α-selenoamino acids.

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Photocatalyst-Free Visible-Light-Promoted C–H Selenylation of Pyrazolo[1,5-a]pyrimidines

et al. 2023

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Nickel-Сatalyzed Carbon–Selenium Bond Formations under Mild Conditions

Cited by 3 publications

References 48 publications

Cluster Preface: Special Issue Honoring Masahiro Murakami’s Contributions to Science

Cluster Preface: Special Issue Honoring Masahiro Murakami’s Contributions to Science

Bio-inspired Halogen Bonding-Promoted Cross Coupling for the Synthesis of Organoselenium Compounds

Photocatalyst-Free Visible-Light-Promoted C–H Selenylation of Pyrazolo[1,5-a]pyrimidines

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