Nickel, palladium and platinum, survey covering the years 1984 and 1985

Chaloner, Penny A.

doi:10.1016/0022-328x(92)83346-j

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Cited by 8 publications

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[Ni(cod)₂][Al(OR^F)₄], a Source for Naked Nickel(I) Chemistry

et al. 2015

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The straightforward synthesis of the cationic, purely organometallic NiI salt [Ni(cod)2]+[Al(ORF)4]− was realized through a reaction between [Ni(cod)2] and Ag[Al(ORF)4] (cod=1,5‐cyclooctadiene). Crystal‐structure analysis and EPR, XANES, and cyclic voltammetry studies confirmed the presence of a homoleptic NiI olefin complex. Weak interactions between the metal center, the ligands, and the anion provide a good starting material for further cationic NiI complexes.

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[Ni(cod)₂][Al(OR^F)₄], a Source for Naked Nickel(I) Chemistry

et al. 2015

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show abstract

[Ni(cod)₂][Al(OR^F)₄], a Source for Naked Nickel(I) Chemistry

et al. 2015

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The straightforward synthesis of the cationic, purely organometallic NiI-salt [Ni(cod)2]+[Al(ORF)4]– was realized through a reaction between Ni(cod)2 and Ag[Al(ORF)4]. Crystal structure, EPR, XANES and cyclic voltammetry confirmed the presence of a homoleptic NiI-olefin complex. Weak interactions between the metal centre, the ligands and the anion provide a good starting material for further cationic NiI-chemistry.

show abstract