Abstract:With the increasing demand for homoallylic silanes and allylic silanes,
the highly efficient and regioselective hydrosilylations of conjugated
dienes are urgently needed. Herein, we developed a Ni-catalyzed
regiodivergent hydrosilylation of aromatic conjugated dienes by
adjusting the temperature and ligands. Under low temperature (-30 oC),
an eternal-ligand-free system (Ni/t-BuOK) can efficiently facili-tate
the 3,4-anti-Markovnikov hydrosilylation to provide homoallylic silanes
via electrophilic activation pr… Show more
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