Nickel-catalyzed isomerization of 2-methyl-3-butenenitrile to 3-pentenenitrile: A kinetic study using in situ FTIR-ATR spectroscopy

Bini, Laura; Houben, Eje; Pidko, Evgeny A.; Müller, Christian; Vogt, Dieter

doi:10.1016/j.cattod.2009.08.017

Search citation statements

Order By: Relevance

Paper Sections

Select...

结果与讨论1

Citation Types

Supporting

Mentioning

Contrasting

Year Published

2012

2019

Publication Types

Select...

Article4

Relationship

Self Cite0

Independent4

Authors

Journals

Cited by 4 publications

(1 citation statement)

References 32 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Table 1 Effect of various temperatures on the title reaction [22] . (2) Reaction (3) Reaction (4) Reaction (5) Reaction (6) Scheme 3 [23] , Scheme 4 列出了 3PN 的几种同分异构体的相对能量对比. …”

Section: 结果与讨论mentioning

confidence: 99%

Nickel(0)-Catalyzed Equilibrium Reaction of 3-Pentenenitrile

Jian-xun¹,

Shi²,

Hu³

et al. 2012

Chin. J. Org. Chem.

View full text Add to dashboard Cite

China Pingmei Shenma Energy and Chemical Group Nylon Chemical Company, Pingdingshan 467013)Abstract The equilibrium reaction of 3-pentenenitrile was carried out in the system containing Ni(0), P-ligand and anhydrous ZnCl 2 . The equilibrium state of 3-pentenenitrile was affected by factors such as reaction temperatures and different ligands, which were investigated. The FTIR-ATR was used to monitor the reaction process of 3-pentenenitrile turning into 2-methylglutaronitrile and adiponitrile in absence of HCN and the possible reaction mechanism was proposed.

show abstract

Section: 结果与讨论mentioning

confidence: 99%