Nickel-based metal-organic frameworks as versatile heterogeneous catalysts: A comprehensive exploration in diverse organic transformations

Goyal, Srashti; Kumar, Parveen; Kumar, Gourav; Soni, Akta; Nemiwal, Meena

doi:10.1016/j.tet.2024.133979

Cited by 1 publication

(1 citation statement)

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“…Over the past few decades, an emergent class of hybrid extremely ordered crystalline porous materials, metal-organic frameworks (MOFs) have gained significant attention for their prospective applications in various fields such as ion exchange, [1][2][3][4] molecular recognition, [5,6] heterogeneous catalysis, [7][8][9][10][11][12][13][14] as well as in delivering medications, [15][16][17] separating substances, and storing gases. [18][19][20][21] Although the utilization of MOFs in catalysis is a relatively new field of study, numerous organic reactions have already been conducted using MOF catalysts or as supports for catalysis, spanning from carboncarbon to carbon-heteroatom synthesis methods.…”

Section: Introductionmentioning

confidence: 99%

Review on the Catalytic Significance of Zr‐Based Metal‐Organic Frameworks as Potential Catalyst for Various Organic Transformations

Bindal,

Soni,

Kumar

et al. 2024

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Within the extensive array of metal‐organic frameworks (MOFs), Zr‐based MOFs stand out as particularly promising materials due to their diverse structures, exceptional stability, and intriguing properties. These MOFs are currently in the early stages of development, but noteworthy strides have been achieved in recent years. This overview focuses on the progress in Zr‐MOFs since 2012, covering design, synthesis, and applications in various reactions such as C−H activation, oxidation, C−C, and C−N coupling approaches. Different Zr‐MOF structural variants are explained in terms of Zr‐based secondary building units and a variety of organic ligands. The review highlights the roles that Zr‐MOFs play in catalysis by highlighting their uses as porous carriers, molecule adsorption, and separation. It is anticipated that this kind of concentrated review on Zr‐MOFs would offer important direction for next studies investigating MOFs for catalytic applications.

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