Nickel based metal-organic framework as catalyst for chemical fixation of CO2 in oxazolidinone synthesis

Helal, Aasif; Fettouhi, Mohammed; Arafat, Md. Eyasin; Khan, Mohd Yusuf; Muraza, Oki

doi:10.1016/j.jcou.2021.101603

Cited by 36 publications

(37 citation statements)

References 35 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…[103] Numerous adsorbents have been reported for CO 2 capture, including zeolites, [93,95,104] ceramics, [105,106] carbonates, [107,108] metal and metal oxides, [24,25] carbonaceous materials, [100,109,110] amines, hydroxides, [111,112] polymers, [113,114] ionic liquids, [115] covalent organic frameworks, [116] and metal-organic frameworks (MOFs). [117][118][119][120][121][122][123][124][125][126][127] Acid-base neutralization reactions also play a key role in capturing CO 2 . CO 2 is acidic, whereas most of the other constituents (N 2 , H 2 O, and HCs) in the flue gas are neutral.…”

Section: Sapo-34 For Co 2 Capture and Separationmentioning

confidence: 99%

A Review on SAPO‐34 Zeolite Materials for CO₂ Capture and Conversion

Usman

Ghanem

Shah

et al. 2022

The Chemical Record

View full text Add to dashboard Cite

Among several known zeolites, silicoaluminophosphate (SAPO)‐34 zeolite exhibits a distinct chemical structure, unique pore size distribution, and chemical, thermal, and ion exchange capabilities, which have recently attracted considerable research attention. Global carbon dioxide (CO2) emissions are a serious environmental issue. Current atmospheric CO2 level exceeds 414 parts per million (ppm), which greatly influences humans, fauna, flora, and the ecosystem as a whole. Zeolites play a vital role in CO2 removal, recycling, and utilization. This review summarizes the properties of the SAPO‐34 zeolite and its role in CO2 capture and separation from air and natural gas. In addition, due to their high thermal stability and catalytic nature, CO2 conversions into valuable products over single metal, bi‐metallic, and tri‐metallic catalysts and their oxides supported on SAPO‐34 were also summarized. Considering these accomplishments, substantial problems related to SAPO‐34 are discussed, and future recommendations are offered in detail to predict how SAPO‐34 could be employed for greenhouse gas mitigation.

show abstract

Section: Sapo-34 For Co 2 Capture and Separationmentioning

confidence: 99%

A Review on SAPO‐34 Zeolite Materials for CO₂ Capture and Conversion

Usman

Ghanem

Shah

et al. 2022

The Chemical Record

View full text Add to dashboard Cite

show abstract

“…Moreover, it was found to be recyclable for five consecutive cycles. Helal et al [103] . reported a Ni‐BTC MOF (Figure 13) with trimesic acid as a linker, which on thermal activation generates coordinatively unsaturated nickel sites that act as a Lewis acid for the formation of bioactive oxazolidinone from epoxides and aromatic amines in the presence of CO 2 in good yield.…”

Section: Application In Co2 Conversionmentioning

confidence: 99%

Potential Applications of Nickel‐Based Metal‐Organic Frameworks and their Derivatives

Helal

Shah

Usman

et al. 2022

The Chemical Record

Self Cite

View full text Add to dashboard Cite

Metal‐Organic Frameworks (MOFs), a novel class of porous extended crystalline structures, are favored in different fields of heterogeneous catalysis, CO2 separation and conversion, and energy storage (supercapacitors) due to their convenience of synthesis, structural tailor‐ability, tunable pore size, high porosity, large specific surface area, devisable structures, and adjustable compositions. Nickel (Ni) is a ubiquitous element extensively applied in various fields of catalysis and energy storage due to its low cost, high abundance, thermal and chemical stability, and environmentally benign nature. Ni‐based MOFs and their derivatives provide us with the opportunity to modify different properties of the Ni center to improve their potential as heterogeneous catalysts or energy storage materials. The recent achievements of Ni−MOFs and their derivatives as catalysts, membrane materials for CO2 separation and conversion, electrode materials and their respective performance have been discussed in this review.

show abstract

“…The fluorescein hydrazide was synthesized using the methods given in the literature and characterized by the 1 H and 13 C NMR (Scheme 1) (Figures S1 and S2). The Ni(MOF) was prepared according to the method followed in the literature [46]. Then, it was activated by evacuation at a high temperature to de-coordinate the aqua ligands from the nickel clusters and generate coordinately unsaturated sites (CUS).…”

Section: Synthesis and Characterization Of Fh@ni(mof)mentioning

confidence: 99%

“…The Ni(MOF) [Ni 3 (BTC) 2 (H 2 O) 3 ]•(DMF) 3 (H 2 O) 3 was prepared by the same method as that reported in the literature [46]. Ni-MOF was synthesized by dissolving Ni(NO 3 ) 2.…”

Section: Synthesis Of Ni(mof)mentioning

confidence: 99%

See 1 more Smart Citation

Fluorescein Hydrazide-Appended Metal–Organic Framework as a Chromogenic and Fluorogenic Chemosensor for Mercury Ions

et al. 2021

Self Cite

View full text Add to dashboard Cite

In this work, we prepared a fluorescein hydrazide-appended Ni(MOF) (Metal–Organic Framework) [Ni3(BTC)2(H2O)3].(DMF)3(H2O)3 composite, FH@Ni(MOF). This composite was well-characterized by PXRD (powder X-ray diffraction), FT-IR (Fourier transform infrared spectroscopy), N2 adsorption isotherm, TGA (thermogravimetric analysis), XPS (X-ray photoelectron spectroscopy), and FESEM (field emission scanning electron microscopy). This composite was then tested with different heavy metals and was found to act as a highly selective and sensitive optical sensor for the Hg2+ ion. It was found that the aqueous emulsion of this composite produces a new peak in absorption at 583 nm, with a chromogenic change to a pink color visible to the naked eye upon binding with Hg2+ ions. In emission, it enhances fluorescence with a fluorogenic change to green fluorescence upon complexation with the Hg2+ ion. The binding constant was found to be 9.4 × 105 M−1, with a detection limit of 0.02 μM or 5 ppb. This sensor was also found to be reversible and could be used for seven consecutive cycles. It was also tested for Hg2+ ion detection in practical water samples from ground water, tap water, and drinking water.

show abstract

Nickel based metal-organic framework as catalyst for chemical fixation of CO2 in oxazolidinone synthesis

Cited by 36 publications

References 35 publications

A Review on SAPO‐34 Zeolite Materials for CO₂ Capture and Conversion

A Review on SAPO‐34 Zeolite Materials for CO₂ Capture and Conversion

Potential Applications of Nickel‐Based Metal‐Organic Frameworks and their Derivatives

Fluorescein Hydrazide-Appended Metal–Organic Framework as a Chromogenic and Fluorogenic Chemosensor for Mercury Ions

Contact Info

Product

Resources

About

Nickel based metal-organic framework as catalyst for chemical fixation of CO2 in oxazolidinone synthesis

Cited by 36 publications

References 35 publications

A Review on SAPO‐34 Zeolite Materials for CO2 Capture and Conversion

A Review on SAPO‐34 Zeolite Materials for CO2 Capture and Conversion

Potential Applications of Nickel‐Based Metal‐Organic Frameworks and their Derivatives

Fluorescein Hydrazide-Appended Metal–Organic Framework as a Chromogenic and Fluorogenic Chemosensor for Mercury Ions

Contact Info

Product

Resources

About

A Review on SAPO‐34 Zeolite Materials for CO₂ Capture and Conversion

A Review on SAPO‐34 Zeolite Materials for CO₂ Capture and Conversion