Magnetars are young, magnetically-powered neutron stars possessing the strongest magnetic fields in the Universe. Fast Radio Bursts (FRBs) are extremely intense millisecond-long radio pulses of primarily extragalactic origin, and a leading attribution for their genesis focuses on magnetars. A hallmark signature of magnetars is their emission of bright, hard X-ray bursts of sub-second duration. On April 27 th 2020, the Galactic magnetar SGR J1935+2154 emitted hundreds of X-ray bursts in a few hours. One of these temporally coincided with an FRB, the first detection of an FRB from the Milky Way. Here we present spectral and temporal analyses of 24 X-ray bursts emitted 13 hours prior to the FRB and seen simultaneously with NASA's NICER and Fermi/GBM missions in their combined energy range, 0.2 keV -30 MeV. These broadband spectra permit direct comparison with the spectrum of the FRB-associated X-ray burst (FRB-X). We demonstrate that all 24 NICER/GBM bursts are very similar temporally, albeit strikingly different spectrally, from FRB-X. The singularity of the FRB-X burst is perhaps indicative of an uncommon locale for its origin. We suggest that this event originated in quasi-polar open or closed magnetic field lines that extend to high altitudes.SGR J1935+2154 was discovered in 2014, when it emitted a few short, hard X-ray, magnetar-like bursts. Follow-up X-ray observations revealed the source spin period (P=3.24 s) and period derivative (dP/dt=1.43x10 -11 s/s). Attributing this spin evolution to magnetic dipole torques on the rotation of the neutron star, a standard practice for pulsars and magnetars 1,2 , it implies a very large surface dipole magnetic field, B~2.2x10 14 G, and a spin down age, τ=3.6 kyr, thus confirming the magnetar nature of this source 3 . The source became active again 4 in May 2015, May and June 2016, and December 2019. The source activity steadily increased with time, emitting larger numbers of bursts, brighter on average than the ones detected during the preceding activation 5 . On April 27 th 2020, SGR J1935+2154 entered yet another active period, the most prolific so far. It comprised a long-lasting burst storm, with at least a few hundred bursts observed within a few hours 6-8 . The 1-25 keV persistent emission of the source was significantly enhanced subsequent to this storm over a period lasting several weeks 7,9 .We observed SGR J1935+2154 with the NICER X-ray Timing Instrument 10 (0.2-12 keV) onboard the International Space Station on April 28, from 00:40:58 UTC until 00:59:36 UTC (~19 minutes), covering just the tail end of the storm. This NICER observation revealed over 200 bursts 7 emitted by SGR J1935+2154, which was also visible to the Fermi Gamma-ray Burst Monitor (GBM; 8 keV -30 MeV). Thirteen hours after the NICER observation, concurrent with a magnetar X-ray burst 11-13 , a Fast Radio Burst (FRB) was detected with the CHIME 14 and STARE2 15 radio telescopes, though no persistent pulsed radio emission was observed in subsequent observations by FAST 16 . The FRB-associated X-...