Ni Oxidation State and Ligand Saturation Impact on the Capability of Octaazamacrocyclic Complexes to Bind and Reduce CO2

Abstract

Two 15-membered octaazamacrocyclic nickel(II) complexes are investigated by theoretical methods to shed light on their affinity forwards binding and reducing CO2. In the first complex 1[NiIIL]0, the octaazamacrocyclic ligand is grossly unsaturated (π-conjugated), while in the second 1[NiIILH]2+ one, the macrocycle is saturated with hydrogens. One and two-electron reductions are described using Mulliken population analysis, quantum theory of atoms in molecules, localized orbitals, and domain averaged fermi holes, including the characterization of the Ni-CCO2 bond and the oxidation state of the central Ni atom. It was found that in the [NiLH] complex, the central atom is reduced to Ni0 and/or NiI and is thus able to bind CO2 via a single σ bond. In addition, the two-electron reduced 3[NiL]2− species also shows an affinity forwards CO2.

Isomerization pathway of a C–C sigma bond in a bis(octaazamacrocycle)dinickel(II) complex activated by deprotonation: a DFT study

“…Density functional theory (DFT) calculations were performed to further support the assignment of species generated after reduction [ 35 ]. In a follow-up work, the analysis of the relationship between the electronic structure of the 15-membered octaazamacrocyclic nickel complexes and their affinity for CO 2 binding was addressed [ 33 , 35 , 36 ].…”

Isomerization pathway of a C-C sigma bond dinickel(II) bis(octaazamacrocyclic) complex activated by deprotonation - a DFT study

“…Theoretical insights into the electronic structure of the parent nickel complexes and their CO 2 adducts were offered from the perspective of localized orbitals, domain averaged fermi holes (DAFH), and frontier orbitals [22].…”