Abstract:A new uranyl tetrachloride salt with chemical formula, (NH4)2[UO2Cl4]·2H2O, namely, diammonium uranyl tetrachloride dihydrate, 1, was prepared and crystallized via slow evaporation from a solution of 2 M hydrochloric acid. As confirmed by powder X-ray diffraction, the title compound crystallizes with an ammonium chloride impurity that formed as a result of the breakdown of a triazine precursor. The (UO2Cl4)2− dianion is charge balanced by ammonium cations, while an extensive hydrogen-bond network donated from … Show more
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