Inorganic Chemistry Communications

2011

DOI: 10.1016/j.inoche.2011.03.068

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New types of the germanium-capped clathrochelate iron(II) and cobalt(III) tris-dioximates: The synthesis, structure and electrochemical properties

Yan Z. Voloshin

¹

,

Sergey V. Korobko

²

,

Alexander V. Dolganov

³

et al.

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Cited by 16 publications

References 16 publications

(26 reference statements)

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Synthesis of the Penta‐ and Hexacoordinate Germanium( IV ) Complexes

2023

Organogermanium Compounds

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No abstract

Synthesis of the Penta‐ and Hexacoordinate Germanium( IV ) Complexes

2023

Organogermanium Compounds

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Borophosphonate Cages: Easily Accessible and Constitutionally Dynamic Heterocubane Scaffolds

et al. 2012

Chemistry A European J

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A versatile and experimentally facile procedure for the synthesis of borophosphonate cages of the general formula [tBuPO(3)BR'](4) is described. The method involves heating of tert-butylphosphonic acid with a boronic acid in toluene to give borophosphonates in [4+4] condensation reactions. The products display a heterocubane structure with bent P-O-B bridges as evidenced by crystallographic analyses. Scrambling experiments show that the borophosphonate cages are constitutionally dynamic scaffolds with exchange reactions occurring on the hour time scale at room temperature. The cages can be decorated with reactive groups such as aldehydes. Our results demonstrate that borophosphonate cages are interesting building blocks for dynamic covalent chemistry.

Encapsulation by Covalent Capsules

¹

,

²

,

2016

The Encapsulation Phenomenon

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