New Tri- and Pentanuclear Osmium Clusters from [Os3(CO)10(NCMe)2] and Pyrrolidine: Reactivity and X-ray Structure of [HOs3(CO)9(µ,κ2-N=C(CH3)C=NCH2CH2CH2)] and [H3Os5(CO)14(µ,η1,κ1-N=CCH2CH2CH2)]

Synthesis of a diruthenium μ-η4-α-diimine complex via dehydrogenative coupling of cyclic amines and its role in dehydrogenative oxidation of pyrrolidine

“…Rosenberg, Kabir and co-workers reported C–C bond formation at the imidoyl carbon with diazomethane, 23 2-butyne, 24 and acetonitrile. 25 We reported that complex 3c reacts with H 2 O to yield bis(μ-hydroxo) complex 4 with the liberation of ε-caprolactam. 22 In terms of related bridging pyridyl complexes, Moore et al .…”