New Trends in Layered Zeolites

Abstract

Layered zeolites, with a flexible and changeable interlayer connection, can be modified to give a great number of derivative structures with enlarged pore sizes or enhanced external surface areas, via swelling, delamination, pillaring, or silylation. In recent years, great efforts have been devoted to the synthesis of novel-layered zeolite precursors, by using the specially designed bifunctional amphiphilic surfactants as the structure-directing agents or through the selective degradation of double four ring-containing germanosilicates. In addition, the novel modifications, such as mild delamination, interlayer expansion assisted by deconstruction-reconstruction, and layer-stacking reorganization by dissolution-recrystallization, have also been developed to create more derivatives while achieving better preservation of layer structures. Recent progresses in the field of layered zeolites are summarized in this chapter, and the challenges for future development are also proposed.

Enumeration of Subperiodic Zeolitic Tetrahedral Frameworks. III. Layers, Rods, Tubes, and Clusters

“…In addition to chemical discovery, there have been vigorous efforts to identify hypothetical zeolite frameworks with plausibly low computed energies of formation that could be realizable. − For a comprehensive discussion of earlier databases and methods, see Treacy et al and the references therein. , Significant progress has been made in synthesizing and interconnecting zeolitic layers to form so-called “unfeasible zeolites.” The intermediate layer structures have hydroxy terminations. − …”