2014
DOI: 10.1002/zaac.201300666
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New Ternary La2Sb‐Type Compounds, ScRESb (RE = La, Ce, Pr, Nd, Sm, Tb), and the Oxygen Stuffed Variant Sc4Yb4Sb4O

Abstract: The compounds ScLnSb (Ln: La, Ce, Pr, Nd, Sm, Tb) are prepared by solid state reaction of Sc metal and LnSb (Ta ampules, 1770 K, 36 h and 1520 K, 60 h).

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Cited by 3 publications
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“…Besides the binary series of RE 2 Sb antimonides and RE 2 Bi bismutides (RE ¼rare earth element), a larger variety of ternary rare earth-containing representatives of this structure are known, e.g. the series of REScSi silicides [3], REScGe germanides [4], and REScSb antimonides [5]. The distinctly smaller size of scandium allows for a complete ordering of the two rare earth sites leading to the formation of the CeScSi-type structure.…”
Section: Introductionmentioning
confidence: 99%
“…Besides the binary series of RE 2 Sb antimonides and RE 2 Bi bismutides (RE ¼rare earth element), a larger variety of ternary rare earth-containing representatives of this structure are known, e.g. the series of REScSi silicides [3], REScGe germanides [4], and REScSb antimonides [5]. The distinctly smaller size of scandium allows for a complete ordering of the two rare earth sites leading to the formation of the CeScSi-type structure.…”
Section: Introductionmentioning
confidence: 99%