1989
DOI: 10.1016/0022-328x(89)87315-2
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New series of functional bicyclic organogermanium compounds

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Cited by 10 publications
(1 citation statement)
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“…However, the poor ability of the hydroxy moiety, as a leaving group, has limited the use of the allyl alcohols as substrates. Correlatively, some efforts have been made in this direction by the use of transition metals such as copper [6], nickel [7], ruthenium (I, II) [8], and palladium (0, II) [910] as the catalyst or by converting the allylic alcohols into esters of inorganic acids, e.g., As 2 O 3 [11], B 2 O 3 [12], CO 2 [1314] . More recently the Lewis acids, such as, Ti(OiPr ) 4 [15], BEt 3 [1619], BPh 3 [20], SnCl 2 [21], and FeCl 3 [22], have also been reported to catalyze these reactions by coordination with the hydroxy moiety, thereby increasing its leaving group ability [2328].…”
Section: Introductionmentioning
confidence: 99%
“…However, the poor ability of the hydroxy moiety, as a leaving group, has limited the use of the allyl alcohols as substrates. Correlatively, some efforts have been made in this direction by the use of transition metals such as copper [6], nickel [7], ruthenium (I, II) [8], and palladium (0, II) [910] as the catalyst or by converting the allylic alcohols into esters of inorganic acids, e.g., As 2 O 3 [11], B 2 O 3 [12], CO 2 [1314] . More recently the Lewis acids, such as, Ti(OiPr ) 4 [15], BEt 3 [1619], BPh 3 [20], SnCl 2 [21], and FeCl 3 [22], have also been reported to catalyze these reactions by coordination with the hydroxy moiety, thereby increasing its leaving group ability [2328].…”
Section: Introductionmentioning
confidence: 99%