New route to alkylaluminum hydroxides via hydrolysis of cyclopentadienylaluminum complexes

Ring‐Opening Polymerization of ε‐Caprolactone Initiated by Aluminium Complexes Based on Pyridine‐Substituted Asymmetric β‐Diketiminate Ligands

“…Complexes 1 – 3 join a small family of aluminium complexes supported by β‐diketiminate ligands . However, compounds 1 – 3 are very rare aluminium complexes bearing asymmetric β‐diketiminate ligands.…”

“…Many different types of ligands, for example, salen, Schiff base, ketiminate, etc., have been used as ancillary ligands to initiate the ROP of ε‐caprolactone. Aluminium complexes with β‐diketiminate ligands have been reported extensively; however, their applications in the ROP of ε‐caprolactone are still less explored . β‐Diketiminate is a kind of large π‐electron‐rich ligand, which can effectively stabilize coordinatively ‐unstable or coordinatively unsaturated central metals.…”

Reaction of sterically encumbered phenols, TEMPO-H, and organocarbonyl insertion reactions with L-AlH2 (L = HC(MeCNDipp)2, Dipp = 2,6-diisopropylphenyl)

“…This is in line with other bdiketiminate-based terminal aluminum monohydroxides in the literature. [33][34][35][36][37][38][39][40][41][42]…”