Sarmiento & Gruber, 2006) by exporting carbon from the surface into the deep ocean via the biological pump. The net efficiency of the biological carbon export depends partly on the relative competitive fitness of a variety of phytoplankton functional types (Kvale et al., 2015b;Kvale et al., 2019). Major groups of these plankton include diazotrophs, coccolithophores, and diatoms. These groups differ in size, shape, and cell wall composition, which affect their sinking velocities (Collins et al., 2014;Klaas & Archer, 2002;Miklasz & Denny, 2010) and thus the amount of carbon exported into the deep ocean (DeVries et al., 2012). Calcifiers (e.g., coccolithophores) and silicifiers (e.g., diatoms) are two functional types thought to exert a dominant influence on global carbon cycling (Matsumoto et al., 2002) due to both their relatively efficient carbon export properties as well as their dominance in the Southern Ocean. Both diatoms and coccolithophores photosynthesize, which leads to oceanic CO 2 uptake. However, coccolithophores also produce calcite platelets, which leads to a decrease in surface alkalinity, that induces a net CO 2 outgassing (a mechanism also called the calcium carbonate counter-pump). Diatoms tend to dominate export production (EP) in the High Nutrient Low Chlorophyll (HNLC) regions. As EP is limited by the availability of Fe in HNLC regions, it has been hypothesized that iron fertilization of HNLC regions might be an efficient mechanism for enhancing ocean sequestration of carbon both in the modern climate as well as in the past (Martin, 1990).It is therefore important to better constrain the response of ecosystems to climatic changes, and in particular the response of diatoms and coccolithophores in the Southern Ocean. One example of significantly