New Physico-Chemical Model of Crystallization With External Influence on the Solidifying Metal (Part 2)

Abstract

Abstract. We have investigated thermodynamic functions of externally induced crystallization of metals. The mechanism of influence of external energy on crystallization of metals is proposed. The model calculations agree satisfactorily with the experiment. The classical model is represented as a particular case of the new concept. The original expression of the external energy is reduced to the analogue of the canonical form of the Gibbs free energy in the classical theory of crystallization, which allows one to explain the phenomenology of the mechanism of the effect of external influences on the stages of the process of nonequilibrium crystallization of metals.