New photoluminescent copolymers of naphthalene-2,7-diol dimethacrylate and N-vinyl-2-pyrrolidone

Podkościelna, Beata

doi:10.1007/s10973-013-3602-5

Cited by 24 publications

(19 citation statements)

References 23 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…The forms were moved into a water bath for 12 hrs at 60°C and then into a heating chamber for 4 hrs at 100°C in order to complete the crosslinking reaction. [17,18] Spectral characterization of the samples ATR-IR spectra were obtained on a Bruker FTIR spectrophotometer TENSOR 27. NMR spectra were recorded on a Bruker 300 MSL Instrument (Bruker, Germany).…”

Section: Experimental Preparation Of Compositions and Their Polymerizmentioning

confidence: 99%

Synthesis, characterization and luminescent properties of new copolymers of dimethacrylate derivatives of naphthalene‐2,7‐diol

Podkościelna

Lipke

Gawdzik

et al. 2014

Polymers for Advanced Techs

Self Cite

View full text Add to dashboard Cite

Synthesis and characterization of new type photoluminescent, bulk copolymers of 2,7-(2-hydroxy-3-methacryloyloxypropoxy)naphthalene (2,7-NAF.DM) with different vinyl comonomers (methyl methacrylate, 2-hydroxyethyl methacrylate, butyl acrylate, divinylbenzene, styrene and N-vinyl-2-pyrrolidone) are presented. The chemical structure of 2,7-NAF.DM was confirmed by NMR, GC-MS and elemental analysis. The copolymers were characterized by ATR and thermal (differential scanning calorimetry) analyses. Their luminescent properties were studied in terms of quantum efficiency (Φ abs ), which was shown to change in the range of 50-90% depending on the type of comonomer. It was found that the green-emitting species in these polymers can be excited directly by low-energy (400-520 nm) photoirradiation. These materials can be applied in the liquid or solid states in the form of powders, films or monoliths.

show abstract

Section: Experimental Preparation Of Compositions and Their Polymerizmentioning

confidence: 99%

Synthesis, characterization and luminescent properties of new copolymers of dimethacrylate derivatives of naphthalene‐2,7‐diol

Podkościelna

Lipke

Gawdzik

et al. 2014

Polymers for Advanced Techs

Self Cite

View full text Add to dashboard Cite

show abstract

“…In comparison with the commonly used adsorbents based on silica gel, polymers are stable throughout the whole pH range, and they can be easily functionalized and have the ability to create specific sorption spaces. In their structure, they combine the most desirable characteristics of porous materials and polymers and consequently are used as various kinds of sorbents [1][2][3][4][5][6][7][8][9]. In the case of specific sorption processes, sorbents should possess functional groups on their surface.…”

Section: Introductionmentioning

confidence: 99%

Thermal properties of TRIM–GMA copolymers with pendant amine groups

Maciejewska

2016

J Therm Anal Calorim

View full text Add to dashboard Cite

The porous copolymers of glycidyl methacrylate crosslinked with trimethylolpropane trimethacrylate were prepared in the form of regular microspheres by suspension-emulsion polymerization. In order to obtain adsorbents bearing functional groups, the porous methacrylate network was modified by subsequent reaction with diethylenetriamine. The thermal behavior of the obtained material was studied using TG and DSC. It was found that the process of modification considerably changed the textural and thermal properties of the polymers. Keywords

show abstract

“…As a result, polymeric microspheres for the HPLC column were obtained [17]. Further studies dealt with the bulk polymerization of 2,7-NAF.DM with Nvinyl-2-pyrrolidone and determination of thermomechanical properties of the obtained copolymers [18]. Then, the research focused on the phenomenon of photoluminescence present in the monomer 2,7-NAF.DM and its copolymers with different commercial monomers [19,20].…”

Section: Introductionmentioning

confidence: 99%

Characteristics of thermal behavior of photoluminescent copolymers studied by the TG/DTG/FTIR coupled method

Podkościelna

Sobiesiak

2016

J Therm Anal Calorim

Self Cite

View full text Add to dashboard Cite

Thermal properties of the photoluminescent copolymers, naphthalene-2,7-diol dimethacrylate derivatives, are presented in this paper. The materials were synthesized by bulk copolymerization of 2,7-(2-hydroxy-3-methacryloyloxypropoxy)naphthalene (2,7-NAF.DM) with four popular vinyl monomers: 2-hydroxyethyl methacrylate (HEMA), butyl acrylate (BA), divinylbenzene (DVB) and styrene (ST). As an initiator, the a,a 0 -azoiso-bis-butyronitrile was used. Thermal stabilities and degradation behaviors of the obtained copolymers were studied by means of the differential scanning calorimetry and thermogravimetric (TG/DTG, in air and in helium atmosphere) analyses. Gases evolved during the thermal treatment were monitored using the TG-FTIR coupled method. The presented copolymers can have potential application as luminophores, protective coatings or fiber-optical sensors.

show abstract

New photoluminescent copolymers of naphthalene-2,7-diol dimethacrylate and N-vinyl-2-pyrrolidone

Cited by 24 publications

References 23 publications

Synthesis, characterization and luminescent properties of new copolymers of dimethacrylate derivatives of naphthalene‐2,7‐diol

Synthesis, characterization and luminescent properties of new copolymers of dimethacrylate derivatives of naphthalene‐2,7‐diol

Thermal properties of TRIM–GMA copolymers with pendant amine groups

Characteristics of thermal behavior of photoluminescent copolymers studied by the TG/DTG/FTIR coupled method

Contact Info

Product

Resources

About