2014
DOI: 10.1021/cm500776x
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New Perovskite-Related Structure Family of Oxide-Ion Conducting Materials NdBaInO4

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Cited by 107 publications
(135 citation statements)
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“…A change in slope is evidenced at temperatures > 500 °C, with the activation energy lowering to 0.71 ± 0.018 eV. At 600 °C the bulk conductivity is comparable to other leading solid oxide electrolyte materials such as Na0.5Bi0.5TiO3 8 , Zr0.92Y0.08O1.96 22 , LAMOX 7 and La0.9Sr0.1Ga0.9Mg0.1O2.9 13 and much greater than perovskite derivatives such as Ba2In2O5 23 and NdBaInO4 24 . NdBaInO4 has an ionic conductivity of  1 x 10 -6 S cm -1 at 600 °C ( Figure 2) although it has recently been shown that it is possible to further enhance the ionic conductivity of NdBaInO4 by substitution of Sr 2+ for Nd 3+ ; Nd0.9Sr0.1BaInO4 has an ionic conductivity of  1 x 10 -4 S cm -1 at 600 °C 25 .…”
Section: Conductivity Of Ba3monbo85mentioning
confidence: 83%
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“…A change in slope is evidenced at temperatures > 500 °C, with the activation energy lowering to 0.71 ± 0.018 eV. At 600 °C the bulk conductivity is comparable to other leading solid oxide electrolyte materials such as Na0.5Bi0.5TiO3 8 , Zr0.92Y0.08O1.96 22 , LAMOX 7 and La0.9Sr0.1Ga0.9Mg0.1O2.9 13 and much greater than perovskite derivatives such as Ba2In2O5 23 and NdBaInO4 24 . NdBaInO4 has an ionic conductivity of  1 x 10 -6 S cm -1 at 600 °C ( Figure 2) although it has recently been shown that it is possible to further enhance the ionic conductivity of NdBaInO4 by substitution of Sr 2+ for Nd 3+ ; Nd0.9Sr0.1BaInO4 has an ionic conductivity of  1 x 10 -4 S cm -1 at 600 °C 25 .…”
Section: Conductivity Of Ba3monbo85mentioning
confidence: 83%
“…2) which exhibits predominantly oxide ion conductivity over the pO2 range 3.0 x 10 -19 to 3.2 x 10 -11 atm 24 . EMF and conductivity versus oxygen partial pressure measurements, give evidence that oxide ionic conductivity is observed for Ba3MoNbO8.5 over the pO2 range 10 -20 -1 atm at 600 C.…”
Section: Discussionmentioning
confidence: 99%
“…In search of highly conductive electrolyte materials remains a major task for researchers working on energy materials. [1][2][3][4] In this paper, we report the new phenomenon that an electronic conductor, such as -LiFeO 2 can be converted into an ionic conductor through the formation of a composite with an insulator -LiAlO 2 .…”
Section: Introductionmentioning
confidence: 97%
“…Since the oxide-ion conduction paths in the crystal structure are governed by the cation network, high oxide-ion conduction occurs in a limited number of crystal structure families, such as fluorite-, 24) Discovery of a new structure family of oxide-ion conductors is therefore important for further development. 25) 28) There are many reports of oxide-ion conductors containing Ga 3+ and Ge…”
Section: Introductionmentioning
confidence: 99%