New palladium complexes with rigid scorpion-type ligands. Crystal structure of complexes [Pd(η3-2-CH3C3H4)(bpz*mPh)](CF3SO3) and [Pd(bpz*mpy)2](BF4)2. bpz*mPh=phenyl-bis(3,5-dimethylpyrazol-1-yl)methane; bpz*mpy=pyridin-2-yl-bis(3,5-dimethylpyrazol-1-yl)methane

Arroyo, Nieves; Torre, Felipe Gómez-de la; Jalón, Félix A.; Manzano, Blanca R.; Moreno-Lara, Belén; Rodrı́guez, Ana

doi:10.1016/s0022-328x(00)00160-1

Cited by 43 publications

(22 citation statements)

References 25 publications

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“…As expected, the presence of the allyl groups forces the nitrogen atoms to adopt a cis disposition. The orientation of the allyl groups in the terminal fragments is the same as that found in similar derivatives:, that is, with the allylic methyl group pointing towards the α‐substituent (pyridine in these complexes). The dihedral angles between the PdNN plane and the plane of the allyl group range from 110.4 to 119.1° in such a way that the C(central) to CH 3 vector points away from the metal.…”

Section: Ligands Of Type II and Iiimentioning

confidence: 53%

“…Interconversion between the isomers was detected at room temperature. We have previously reported the synthesis of several palladium(II) complexes with the ligand Ib [ Ib = HC(pz*) 2 (2py), pz* = 3,5‐dimethylpyrazolyl]: namely [PdCl 2 ( Ib )] ( 3 ), [PdClMe( Ib )] ( 4 ), [Pd(C 6 F 5 ) 2 ( Ib )] ( 5 ), [(η 3 ‐2Me‐allyl)Pd( Ib )]OTf ( 6 ) and [Pd( Ib ) 2 ](BF 4 ) 2 ( 7 ). In the cases of 3 , 4 , 5 and 6 , the pyridine ring was uncoordinated.…”

Section: Ligands Of Type Imentioning

confidence: 99%

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Bis(pyrazol‐1‐yl)(pyridin‐x‐yl)methane Ligands – Mono‐ or Ditopic Ligands in Complexes and Supramolecular Frameworks

et al. 2016

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Bis(pyrazol-1-yl)(pyridin-x-yl)methane ligands give rise to a rich variety of complexes with a wide range of transition metals. The derivatives with x = 2 act as monotopic and tripodal ligands. In the cases of ligands with x = 3 or 4, tripodal coordination is no longer possible and they generally behave as ditopic ligands that bridge two metal centres in cyclic dimers and trinuclear or polymeric species. The metal geometry has a clear influence on the type of compound formed. Ligands with [a] Universidad de the group of Professor Bruno Chaudret, in the field of nonclassical hydrides of Ru. He has been full Professor at the University of Castilla-La Mancha since 2003. Currently he is co-leader of the Applied Coordination Chemistry group in the UCLM together with Professor Blanca R. Manzano. He has co-authored more than 100 publications and three book chapters. His research topics include homogeneous catalysis and supramolecular and medicinal chemistry. The polypyrazolylmethane and polypyrazolylborate derivatives have been and are being used as ligands in all of these research fields of interest. Dr. M a Carmen Carrión obtained her BSc (1999) and PhD (2004) from the University of Castilla-La Mancha, under the supervision of Profs. F. Jalón and B. R. Manzano. From 2005 to 2007 she held a postdoctoral fellowship at the University of St. Andrews in the group of Professor D. Cole-Hamilton. She returned to the University of Castilla-La Mancha as a "Juan de la Cierva" postdoctoral researcher (2007) and since 2010 she has held an INCRECYT contract. Her current work is mainly focused on the synthesis of supramolecular entities for gas-storage or catalytic uses, the photocatalytic production of hydrogen from water by use of transition metals, and the synthesis of organometallic drugs for the interaction with the G-quadruplex structure of DNA. Gema Durá was born in Alicante, Spain. She received her BSc (2008) from the University of Castilla-La Mancha. She obtained her Ph.D. in 2014 under the supervision of Profs. Felix Jalon and M. Carmen Carrion at the same university, with a FPU studentship, working on the supramolecular chemistry and synthesis of metal-organic frameworks (MOFs). In 2011 she spent three months working on MOF chemistry in Schröder's group in Nottingham, England. In 2014 she was awarded a postdoctoral fellowship funded by the Junta de Castilla-La Mancha (JCLM) to join the group of Michael North in GCCE at the University of York, working with carbonaceous materials as CO 2 capture agents. Since July 2015 she has been a member of the DAF Group (Newcastle University with David Fulton) as a postdoctoral researcher and is currently focused on developing new hydrogel materials based on polymeric proteins for applications in industry and medicine. 2273 Scheme 1. Structures of ligands I-V and the types of coordination found. Scheme 2. Different approaches to the synthesis of bis(pyrazol-1-yl)(pyridinx-yl)methane ligands. Ligands of Type IBis(pyrazolyl)methane ligands containing a pyridin-2-yl fragment in the central...

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Section: Ligands Of Type II and Iiimentioning

confidence: 53%

Section: Ligands Of Type Imentioning

confidence: 99%

Bis(pyrazol‐1‐yl)(pyridin‐x‐yl)methane Ligands – Mono‐ or Ditopic Ligands in Complexes and Supramolecular Frameworks

et al. 2016

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“…Rigid ligands including pyrazole are some of the most desirable ligands to biologists and bioinorganic chemists for specific functions, such as catalysis and fluxional behaviour (Zhang et al, 2009;Arroyo et al, 2000), and also in electrochemistry (Morin et al, 2011). Recently, there has been considerable interest in the use of multifunctional ligands containing substituted pyrazole groups because of their potential applications in catalysis, and their ability to form complexes that mimic structural and catalytic functions in metalloproteins (García-Antó n et al, 2003;Mukherjee, 2000;Pal et al, 2005;Shaw et al, 2004).…”

Section: Structure Descriptionmentioning

confidence: 99%

Dichlorido{N,N,N′-trimethyl-N′-(1H-pyrazol-1-yl-κN ²)methyl]ethane-1,2-diamine-κ² N,N′}copper(II) methanol monosolvate

Singh¹,

Ali

Faizi

et al. 2019

IUCr Data

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In the title compound, [CuCl2(C9H18N4)]·CH3OH, the central CuII ion is coordinated by three N atoms from the pyrazole derivative ligand and two chloride co-ligands. The coordination geometry around the CuII ion is distorted trigonal–bipyramidal. In the crystal, the molecules are linked by C—H...O, C—H...Cl and O—H...Cl hydrogen bonds, forming a three-dimensional framework with the lattice solvent molecule.

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“…Rigid ligands have captivated attention not only because of their various coordination possibilities and high structural stability, but also because of their potential applications in electrochemistry (Morin et al, 2011), catalysis (Zhang et al, 2009), and fluxional behaviour (Otten et al, 2009;Arroyo et al, 2000). In addition, N-heterocyclic rigid scorpion-type ligands have attracted increased attention due to their nitrogen coordination sites (Reger et al, 2005;Liu et al, 2011).…”

Section: S1 Commentmentioning

confidence: 99%

Bis{2-[bis(3,5-dimethyl-1H-pyrazol-1-yl-κN ²)methyl]pyridine-κN}cobalt(II) dinitrate

Xiao¹,

Song²,

Sun³

et al. 2012

Acta Cryst E

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New palladium complexes with rigid scorpion-type ligands. Crystal structure of complexes [Pd(η3-2-CH3C3H4)(bpzmPh)](CF3SO3) and [Pd(bpzmpy)2](BF4)2. bpzmPh=phenyl-bis(3,5-dimethylpyrazol-1-yl)methane; bpzmpy=pyridin-2-yl-bis(3,5-dimethylpyrazol-1-yl)methane

Cited by 43 publications

References 25 publications

Bis(pyrazol‐1‐yl)(pyridin‐x‐yl)methane Ligands – Mono‐ or Ditopic Ligands in Complexes and Supramolecular Frameworks

Bis(pyrazol‐1‐yl)(pyridin‐x‐yl)methane Ligands – Mono‐ or Ditopic Ligands in Complexes and Supramolecular Frameworks

Dichlorido{N,N,N′-trimethyl-N′-(1H-pyrazol-1-yl-κN ²)methyl]ethane-1,2-diamine-κ² N,N′}copper(II) methanol monosolvate

Bis{2-[bis(3,5-dimethyl-1H-pyrazol-1-yl-κN ²)methyl]pyridine-κN}cobalt(II) dinitrate

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New palladium complexes with rigid scorpion-type ligands. Crystal structure of complexes [Pd(η3-2-CH3C3H4)(bpz*mPh)](CF3SO3) and [Pd(bpz*mpy)2](BF4)2. bpz*mPh=phenyl-bis(3,5-dimethylpyrazol-1-yl)methane; bpz*mpy=pyridin-2-yl-bis(3,5-dimethylpyrazol-1-yl)methane

Cited by 43 publications

References 25 publications

Bis(pyrazol‐1‐yl)(pyridin‐x‐yl)methane Ligands – Mono‐ or Ditopic Ligands in Complexes and Supramolecular Frameworks

Bis(pyrazol‐1‐yl)(pyridin‐x‐yl)methane Ligands – Mono‐ or Ditopic Ligands in Complexes and Supramolecular Frameworks

Dichlorido{N,N,N′-trimethyl-N′-(1H-pyrazol-1-yl-κN 2)methyl]ethane-1,2-diamine-κ2 N,N′}copper(II) methanol monosolvate

Bis{2-[bis(3,5-dimethyl-1H-pyrazol-1-yl-κN 2)methyl]pyridine-κN}cobalt(II) dinitrate

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New palladium complexes with rigid scorpion-type ligands. Crystal structure of complexes [Pd(η3-2-CH3C3H4)(bpzmPh)](CF3SO3) and [Pd(bpzmpy)2](BF4)2. bpzmPh=phenyl-bis(3,5-dimethylpyrazol-1-yl)methane; bpzmpy=pyridin-2-yl-bis(3,5-dimethylpyrazol-1-yl)methane

Dichlorido{N,N,N′-trimethyl-N′-(1H-pyrazol-1-yl-κN ²)methyl]ethane-1,2-diamine-κ² N,N′}copper(II) methanol monosolvate

Bis{2-[bis(3,5-dimethyl-1H-pyrazol-1-yl-κN ²)methyl]pyridine-κN}cobalt(II) dinitrate