New N-heterocyclic aroyl hydrazone containing 4-oxopiperidine nucleus and its metal complexes: synthesis, spectroscopic, thermal, DFT, molecular docking and antimicrobial studies
Gajanan Dongare,
Anand Aswar
Abstract:In order to resist the growth of human pathogenic microorganisms, we have synthesized a new N-heterocyclic hydrazone ligand of (E)–N'–(2-hydroxynaphthalen-1-yl)methylene-4-oxopiperidine-1-carbohydrazide (H2L) from the condensation reaction of 4-oxo-1-carbopiperidone hydrazide and 2-hydroxy-1-naphthaldehyde. The ligand reacted with metal salt of (M(II/III).Cl2).nH2O formed the two types of complexes [M(III)C17H19N3O5Cl] and [M(II)C17H20N3O5Cl] adopted octahedral geometry; where M = Cr(III), Fe(III), Mn(II), Co(… Show more
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