New Insights into Photo-Fenton Chemistry: The Overlooked Role of Excited IronIII Species
Minglu Sun,
Peng Zhou,
Shuang Meng
et al.
Abstract:Direct photoreduction of Fe III is a widely recognized route for accelerating Fe III /Fe II cycle in photo-Fenton chemistry. However, most of the wavelengths covering the full spectral range are insufficient to supply enough photon energy for the direct reduction process. Herein, the hitherto neglected mechanism of Fe III reduction that the Fe III indirect reduction pathway initiated by light energy-dependent reactivity variation and reactive excited state (ES) was explored. Evolution of excited-state Fe III s… Show more
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