New functional polymers prepared by ring-opening metathesis polymerization: study of the quenching of luminescence of pyrene end groups by ferrocene or phenothiazine centers in the polymers

Functional Monolithic Materials for Boronate‐Affinity Chromatography via Schrock Catalyst‐Triggered Ring‐Opening Metathesis Polymerization

“…In this reaction, the active catalyst undergoes a Wittig‐type reaction with the aldehyde and transforms into an inactive oxo‐complex that may conveniently be removed. Concomitantly, the functional group attached to the aldehyde is transferred to the respective polymer chain end in the reaction 9–21. In view of the high synthetic potential of the metathesis reaction of Mo‐alkylidenes with aldehydes, we decided to employ this reaction to introduce various functional groups to ROMP‐derived monoliths.…”

Synthesis of end-labeled multivalent ligands for exploring cell-surface-receptor–ligand interactions

“…The attachment of additional, orthogonal functional groups at polymer termini extends the applications of materials generated by ROMP [18][19][20]. For example, selective end-capping molybdenum-carbene-initiated ROMP reactions have facilitated the syntheses of surfaces bearing ROMP-derived polymers [19].…”

Side‐Chain Metal‐Containing Polymers

“…30 compared to emission from 1-vinylpyrene [29]. This thermal behavior is consistent with a block rather than a random copolymer structure.…”

“…Due to the living nature of the polymerization using the Mo catalysts, block copolymers could also be prepared (Scheme 2.2) [28,29]. 2.5).…”