New class of metallacarboranes incorporating the η7-carboranyl ligand

Xie, Zuowei

doi:10.1351/pac200173020361

Pure and Applied Chemistry

2001

DOI: 10.1351/pac200173020361

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New class of metallacarboranes incorporating the η7-carboranyl ligand

Zuowei Xie

Abstract: This article provides an overview of our work on the synthesis, molecular structure, and bonding of a novel class of 13-vertex closo-metallacarboranes incorporating the η 7 -carboranyl ligand. This bonding mode can only be observed in the d 0 /f n transition-metal ions with the proper size.

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Cited by 6 publications

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Diferratricarbaboranes of the subcloso‐[(η⁵‐C₅H₅)₂Fe₂C₃B₈H₁₁] Type, the First Representatives of the 13‐Vertex Dimetallatricarbaborane Series

Grüner

Štı́br

Kivekäs

et al. 2003

Chemistry A European J

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Treatment of the [2‐Cp‐9‐tBuNH‐closo‐2,1,7,9‐FeC3B8H10] (1) ferratricarbollide (Cp = η5‐C5H5−) with Na+ C10H8− in 1,2‐dimethoxyethane (DME) at room temperature produced an air‐sensitive transient anion with a tentatively identified nido‐[tBuNH‐CpFeC3B8H10]2− constitution. In‐situ reaction of this low‐stability ion with [CpFe(CO)2I] or [CpFe(CO)2]2 generated three violet diferratricarbaboranes identified as paramagnetic subcloso complexes [4,5‐Cp2‐‐4,5,1,6,7‐Fe2C3B8H11] (2; yield 2 %), [4,5‐Cp2‐‐4,5,1,7,12‐Fe2C3B8H11] (3; yield 2 %), and [7‐tBuNH‐4,5‐Cp2‐‐4,5,1,7,12‐Fe2C3B8H10] (4; yield 14 %). These first representatives of the 13‐vertex dimetallatricarbaborane family were characterized by EPR and IR spectroscopy, and mass spectrometry, and their structures were determined by X‐ray diffraction analysis.

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Diferratricarbaboranes of the subcloso‐[(η⁵‐C₅H₅)₂Fe₂C₃B₈H₁₁] Type, the First Representatives of the 13‐Vertex Dimetallatricarbaborane Series

Grüner

Štı́br

Kivekäs

et al. 2003

Chemistry A European J

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ChemInform Abstract: New Class of Metallacarboranes Incorporating the η⁷‐Carboranyl Ligand

Xie

2001

ChemInform

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Substituents effect on molecular structures of 13-vertex closo -metallacarboranes of rare earths. Synthesis and structural characterization of metallacarboranes bearing nido - and arachno -carborane ligands

Wang¹,

Wang²,

Cheung³

et al. 2003

Tetrahedron

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New class of metallacarboranes incorporating the η7-carboranyl ligand

Cited by 6 publications

References 4 publications

Diferratricarbaboranes of the subcloso‐[(η⁵‐C₅H₅)₂Fe₂C₃B₈H₁₁] Type, the First Representatives of the 13‐Vertex Dimetallatricarbaborane Series

Diferratricarbaboranes of the subcloso‐[(η⁵‐C₅H₅)₂Fe₂C₃B₈H₁₁] Type, the First Representatives of the 13‐Vertex Dimetallatricarbaborane Series

ChemInform Abstract: New Class of Metallacarboranes Incorporating the η⁷‐Carboranyl Ligand

Substituents effect on molecular structures of 13-vertex closo -metallacarboranes of rare earths. Synthesis and structural characterization of metallacarboranes bearing nido - and arachno -carborane ligands

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New class of metallacarboranes incorporating the η7-carboranyl ligand

Cited by 6 publications

References 4 publications

Diferratricarbaboranes of the subcloso‐[(η5‐C5H5)2Fe2C3B8H11] Type, the First Representatives of the 13‐Vertex Dimetallatricarbaborane Series

Diferratricarbaboranes of the subcloso‐[(η5‐C5H5)2Fe2C3B8H11] Type, the First Representatives of the 13‐Vertex Dimetallatricarbaborane Series

ChemInform Abstract: New Class of Metallacarboranes Incorporating the η7‐Carboranyl Ligand

Substituents effect on molecular structures of 13-vertex closo -metallacarboranes of rare earths. Synthesis and structural characterization of metallacarboranes bearing nido - and arachno -carborane ligands

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Product

Resources

About

Diferratricarbaboranes of the subcloso‐[(η⁵‐C₅H₅)₂Fe₂C₃B₈H₁₁] Type, the First Representatives of the 13‐Vertex Dimetallatricarbaborane Series

Diferratricarbaboranes of the subcloso‐[(η⁵‐C₅H₅)₂Fe₂C₃B₈H₁₁] Type, the First Representatives of the 13‐Vertex Dimetallatricarbaborane Series

ChemInform Abstract: New Class of Metallacarboranes Incorporating the η⁷‐Carboranyl Ligand