New chiral thioether-phosphite ligands and their rhodium-coordination chemistry: steric and electronic properties, dynamic processes and application in catalysis

Abstract

NMR spectra of ligands SP5-7 and of their rhodium-complexes, [Rh(SP5-7)(COD)]BF 4 13 C{ 1 H} NMR spectrum of SP5 (101 MHz, C6D6) 31 P{ 1 H} NMR spectrum of SP5 (162 MHz, C6D6)

Carbohydrate-based N-heterocyclic carbene-metal complexes: a new avenue for sustainable catalysts in organic transformations

“…[20][21][22][23][24][25] Pioneering work involving carbohydrate incorporation into phosphine and phosphate ligands has been well established. [26][27][28][29][30][31] Furthermore, carbohydrates incorporated with NHC ligands have been recently developed. The incorporation of these physiologically active residues into the skeleton of NHC-metal complexes may reduce toxicity while increasing biocompatibility and solubility.…”