Abstract:Sulfuryl fluoride is a gas produced on a multi‐ton scale for its use as a fumigant. In the last decades, it has gained interest in organic synthesis as a reagent with unique properties in terms of stability and reactivity when compared to other sulfur‐based reagents. Sulfuryl fluoride has not only been used for sulfur‐fluoride exchange (SuFEx) chemistry but also encountered applications in classic organic synthesis as an efficient activator of both alcohols and phenols, forming a triflate surrogate, namely a f… Show more
An in situ SO2F2-mediated and palladium-catalyzed method is shown for the decarboxylative dehydrogenation of alkanecarboxylic acids and decarboxylative cross-coupling of arenecarboxylic acids, respectively.
An in situ SO2F2-mediated and palladium-catalyzed method is shown for the decarboxylative dehydrogenation of alkanecarboxylic acids and decarboxylative cross-coupling of arenecarboxylic acids, respectively.
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