Leme. To the project members Kamilla, Gustavo, Sergio, Gabriel, Cléber, Jhon and Juan, for the constructive advises and willingness to help anytime. To the Coordenação de aperfeiçoamento de pessoal de Nível Superior (CAPES) for the conferred scolarship. My grateful extended to all the members and technicians of the Sistemas Cársticos, Isótopos Estáveis, and Petrografia Sedimentar laboratories where the analysis were carried out and also, to all the staff of the IGC/USP. My deep gratitude to my besties: Maria Fernanda for the support, countless advices, for always be there even at the worst ideas, Julisa for understand, hear and always wish the best for me, and Martin for the technical advises and share my worries, for the friendship without boundaries. To my friends, Ximena, Santiago and Rodrigo, for the company and unconditional support. Finally, my heartfelt thanks to my mom Hilda "loyal friend my guardian angel in the sky" to my dad Luis Alfonso for his constant support and example. To My brothers William for giving me strength and helping me and Diego for supporting my constant grumbling and being my accomplice in everything I do. To my nieces and nephew Ana María, María Alejandra, Juan Felipe and María Lucía, for understand, for the unconditional love, this is also for you. Thanks to everyone that help me get here, without you this would not have been possible!