1993
DOI: 10.1080/00222349308215470
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New approach to the description of young's modulus for highly oriented polymers. ii. Relationship between young's modulus and thermal expansion of polymers over a wide temperature range

Abstract: An empirical equation for Young's modulus is proposed. It originates from thermal fluctuations and relates Young's modulus for highly oriented polymers, E, to thermal expansion strain of the segments of macromolecular helices, eT, and to measurement time 7:where Eo is the E value at ET -0, CO is the heat capacity, k is the Boltzmann constant, E , P 0.1, and 70 = (10-'2-10-14)s. The equation may be used for description of the temperature dependences of Young's modulus, E( T ) , at r = constant over a wide tempe… Show more

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Cited by 4 publications
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“…Vettegren et al 28 and Bronnikov et al 29 developed an expression that relates the time and temperature dependent Young's modulus to the material properties of a polymer before loading. Once validated, the empirical expression could be easily incorporated into the joint conductance model, and then the joint conductance model would account for the viscoelastic behavior of polymers.…”
Section: Areas For Future Studymentioning
confidence: 99%
“…Vettegren et al 28 and Bronnikov et al 29 developed an expression that relates the time and temperature dependent Young's modulus to the material properties of a polymer before loading. Once validated, the empirical expression could be easily incorporated into the joint conductance model, and then the joint conductance model would account for the viscoelastic behavior of polymers.…”
Section: Areas For Future Studymentioning
confidence: 99%