Abstract:In the work structure mechanisms of Mn segregation from solid solutions with perovskite-like and spinel structure were investigated. The complex Mn-content oxides are often used as catalysts. Spinels (Mn 3-x Al x O 4) are known as catalysts of deep oxidation. The La 1-x Ca x MnO 3 solid solutions with the perovskite-like structure are catalysts for the partial oxidation of methane. In both systems an active component of catalysts is manganese oxide which is formed under catalytic reaction conditions. Spinel ca… Show more
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