The large spin dependence of the absorption cross section for neutrons by 3 He gas provides a method to polarize neutron beams. For certain applications, such polarized 3 He-based neutron "spin filters" have advantages over conventional neutron optical polarizing methods. Spin filters operate at all neutron wavelengths, can cover a large angular range and/or a large energy range, and decouple neutron polarization from energy selection. Both spin-exchange optical pumping (SEOP) and metastability-exchange optical pumping (MEOP) are currently being employed to polarize 3 He spin filters at various neutron facilities worldwide. We focus on the development and application of SEOP-based neutron spin filters at the National Institute of Standards and Technology (NIST), Center for Neutron Research (NCNR). The combination of long relaxation time spin filter cells, high power spectrally narrowed diode lasers, and the use of Rb/K mixtures have allowed us to reach 3 He polarizations up to 85 % in spin filter cells ≈1 liter in volume. Studies have revealed limits to the achievable polarization from temperature-dependent relaxation and unexplained magnetic field dependence for relaxation in SEOP cells. Applications include neutron scattering methods such as triple-axis spectrometry and small angle neutron scattering, and fundamental neutron physics. In most neutron scattering applications, cells are transported to the beam line and stored in a magnetically shielded solenoid or box. A recent focus has been apparatus for wide-angle neutron polarization analysis. A measurement of the spin-dependence of the neutron-3 He scattering length was performed with a small, polarized 3 He cell located inside a neutron interferometer. A precision measurement of the neutron polarization for this experiment was also performed with a 3 He spin filter. Use of spin filters in high flux neutron beams have revealed beam-induced alkali-metal relaxation and long term effects on SEOP spin filter cells.