Neutralization of Anthropogenic Acidic Particles by NH₃ From Wildfire Over Tropical Peatland

Abstract

Acidity is an essential characteristic of aerosol particles that influences chemical and physical properties. Aerosol particles in tropical Asia, such as Singapore, have been reported as highly acidic due to intense anthropogenic sulfur emissions. At the same time, the region has also been experiencing wildfire over tropical peatlands, which is recognized as an intense source of NH3. Here, we investigated the role of NH3 from wildfire on aerosol particles in Singapore by employing the aerosol mass spectrometric technique. The observation was conducted both during wildfire haze (2015 October and 2019 September–October) and non‐haze (2018 October and 2019 April) periods. The observation result demonstrated that inorganic ionic species in Singapore were neutralized by NH4+ during the haze periods. Namely, the degree of neutralization of aerosol particles (i.e., measured NH4+ concentration/predicted NH4+ concentration by assuming that NH4+ fully neutralized SO42−, NO3−, and Cl−) was lower than 0.77during the non‐haze periods. On the other hand, the corresponding values were higher than 0.93 during the haze periods. In addition, NO3− concentration during the daytime of the haze period in 2015 was higher than that in other observation periods. A thermodynamic model calculation suggested that the regime shifts from the “NH3 sensitive region” to the “NH3 and HNO3 sensitive region” or “HNO3 sensitive region” might have occurred during the haze period. In the future, continuous monitoring of both gas‐ and particle‐phase inorganic chemical species will need to be conducted to investigate the impact of wildfire haze on atmospheric chemical processes in more detail.