Resonance absorption of narrow-bandwidth coherent vacuum UV radiation is applied to hydrogen and deuterium plasmas in a magnetic multipole source to determine populations of rovibronic levels of the electronic molecular ground state as well as atomic densities and temperatures. Variations of atomic densities are investigated as a function of discharge parameters in two different regions of the plasma source: the central region and close to the wall.A strong dependence of the atomic density on pressure and discharge current is observed as well as a considerable difference between the values in the central and the edge regions. The differences in atomic densities between discharges in hydrogen and deuterium are small. The populations of rovibronic levels of H 2 and D 2 -determined only in the central region-do not exhibit significant differences for the levels investigated (v = 2 to 5 for H 2 and v = 3 to 6 for D 2 )-the distributions are close to Boltzmann. Molecular translation temperatures-close to room temperature-are in good agreement with the rotational temperatures determined from the population of the first four rotational states of the v = 2 state of hydrogen and the first six rotational states of the v = 3 state of deuterium. The fraction of cold atoms present in the discharges exhibits a similar temperature.