“…The Cassini mission has revealed a chemically complex ionosphere around Titan. N 2 and CH 4 are ionized and/or dissociated by solar photons or particle irradiation marking the onset of a chain of chemical reactions, which produce hydrocarbon and nitrile ions, heavy positive and negative ions, and eventually aerosols (e.g., Vuitton et al, 2007;Waite et al, 2007;Wahlund et al, 2009;Crary et al, 2009;Ågren et al, 2012;Shebanits et al, 2013;Lavvas et al, 2013;Wellbrock et al, 2013). However, Titan dayside ionospheric models have shown difficulties in reproducing observed electron number densities (e.g., Vigren et al, 2013), as well as the observed number densities of HCNH + , the dominant ion in the main ionosphere (e.g., Vuitton et al, 2009;Westlake et al, 2012).…”