Negative charge-transfer energy in
SrFeO3
revisited with hard x-ray photoemission spectroscopy
D. Takegami,
M. Nakamura,
A. Melendez-Sans
et al.
Abstract:We report hard x-ray photoelectron spectroscopy on SrFeO3 which is one of the classical conducting transition-metal oxides with a noncollinear magnetic structure. The obtained spectra show a detailed charge-transfer (CT) satellite structure, the Fe 2p3/2 main peak exhibits multiplet splitting, and the deterioration signs present in previous reports are absent here, allowing for a better determination of its intrinsic electronic structure. The results are well described by a FeO6 cluster model with a charge-tra… Show more
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